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Phytoremediation and Reuse - Phytoremediation of Contaminated Soil
and Groundwater
Plant -based remediation (phytoremediation) is the use of plants to treat or stabilize
contaminated soils, sediments, or groundwater. Plants can support the process of remediation
in many ways:
• Rhizofiltration — the removal of contaminants by adsorption to plant roots
• Rhizosphere Bioremediation — enhanced microbial degradation of contaminants near plant root
surfaces
• Phytostabilization — erosion control of contaminated soils or hydraulic control through
management of the soil water balance -
• Phytoextraction — removal and concentration of contaminants, generally metals, in plant tissues
• Phytotransformation — plant uptake and transformation of contaminants to less toxic forms
To be effective, phytoremediation projects must successfully integrate both the plant -based
and engineering aspects of a system; this requires an interdisciplinary approach. CH2M HILL
brings together the right team of agricultural and environmental engineers, plant and soil
scientists (agronomy and soil physics, chemistry, management, and classification),
hydrogeologists, and others with the skills to address each remediation project's specific
problems. It is CH2M HILL's combined expertise and the ability to seamlessly integrate the
technical disciplines that makes it unique among firms who use phytoremediation technologies.
Remediation and Reuse of Nitrogen- Contaminated Groundwater
Mill Creek Correctional Facility
For decades, manure from the Mill Creek Correctional Facility dairy was placed in an area
downslope from the barn. As a result, the soil, groundwater, and nearby Mill Creek were
contaminated with nitrogen. Several years ago, a diversion structure and collection system
were constructed to prevent further contamination. The existing soil and groundwater
contamination, however, continued to migrate to Mill Creek.
Technology
To mitigate the problem, CH2M HILL developed a phytoremediation plan using poplar trees and
Phytoremedial
• Phytoremediatic
Phytoremediation o.
Soil and Groundwat
Reuse of Municipal
Biosolids
• Reuse of Indust
Wastewater and
• Hybrid Poplar Al
• Alternative Lam
and Erosion Cor
• Landfill Leachab
• Irrigation and D
Systems
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native hardwoods to take up excess nitrogen compounds associated with manure disposal. The
trees are intended to remove nitrogen from the soil and shallow groundwater system to limit
continued loading to an adjacent creek. A monitoring plan has been prepared so that removal
rates can be quantified. The concept will be expanded to address other nonpoint pollution
problems near the creek. Costs were kept to a minimum through the use of donations of labor
and plants. The local watershed council donated labor to plant and maintain the site, prison
laborers also helped plant trees, and both native cottonwood and hybrid poplar trees were
donated by Howard James Corporation and Mt. Jefferson Farms, Rows of approximately 8,500
poplars and native black cottonwood were planted perpendicular to groundwater flow on 3.5
acres.
Benefit
• Thirsty tree roots will reduce recharge in the area and reduce groundwater flow from the area.
• Water quality in the stream should improve over time because of reduced nitrogen loading.
• This project provides a successful example of a low -cost cooperative remediation effort that can be
replicated by confined animal feeding operations (CAFO) throughout the watershed.
Decontamination of Soil at Decommissioned Oil Refinery
Petroleum Company, Kansas
CH2M HILL assisted with the remediation of a former oil refinery site. In lieu of continued
investment in costly conventional petroleum hydrocarbon remedies, a plant -based treatment
system was designed to make maximum use of natural systems and relatively passive, long-
term remedial action. Hybrid poplar trees were established in test plots to aid the design of a
full scale planting.
Technology
Remediation of petroleum hydrocarbons will be accomplished through rhizosphere
bioremediation. Hybrid poplars will provide a rich environment for soil microorganisms that
will, in turn, degrade petroleum hydrocarbons. The high transpiration rate of hybrid poplars
also helps dewater the soil. This increases the soil volume available to support the remediation
process.
Benefits
• This system will accelerate the degradation and minimize the offsite movement of petroleum
hydrocarbons by providing hydraulic control.
• The remediation costs of this system are dramatically less than those of conventional methods.
• The hybrid poplar tree plantation will dramatically improve the aesthetics and wildlife habitat of this
highly industrialized area.
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Treatment of Oily Waste Through Land Application
Texaco, Anacortes, Washington
CH2M HILL assisted Texaco with design and Resource Conservation and Recovery Act
permitting for the upgrade and expansion of an oily wasteland farm at an operating oil refinery.
The highly monitored site is being managed for biodegradation of oil sludges from refinery
filters, tank bottoms, and other waste generating operations. The site receives greater than 50
inches per year of rainfall and, therefore, required runoff management and cropping for water
consumption. CH2M HILL staff worked closely with site managers and Texaco technical staff to
evaluate the site and historic operations and to develop designs and permit documents for the
upgrades and continued operations.
Technology
The land farm management plan includes measures to monitor and adjust the soil rhizosphere
so that optimal conditions for degradation of oily wastes are maintained. To keep contaminant
concentrations within the target range for maintaining a thriving microbial population, the site
is "loaded" with oily waste in doses that correspond to degradation rates. (Correct site loading
matches the microbe's capacity to consume oily waste with the amount of oil in the soil.)
Agronomy and soil sciences of soil fertility, tilth, aeration, and moisture content are also
managed for optimal capacity. Rotations of grass, grains, and clover crops are planted on the
site two times each year. The crops are managed to enhance rhizosphere microbial activity and
soil moisture content. The crops are seasonally plowed into the soil with the applied waste to
provide a stabilizing "green manure" nutrient source.
Benefits
• Because of proper management, bioremediation of the oily waste on this land farm is extremely cost
effective and has low risk.
• Monitoring data for permit compliance can be reused to make informed decisions for site operations.
Remediation of Diesel - Contaminated Soil Through Cultivation of
Grass and Clover
Daishowa Paper Mill, Port Angeles, Washington
The soil in the railroad engine refueling yard at this paper mill was contaminated from decades
of fuel spills and engine servicing. To reduce contaminant concentration to the point where the
soil could be managed as a bioremediation land farm , CH2M HILL excavated, moved to an
adjacent area, and blended soil from the areas of greatest contamination with dredge spoils
and livestock manure. The soil in areas with lower concentrations of fuel was remediated
through the cultivation of plants onsite. The project included design, permitting, construction
management, operations consulting, and monitoring over a period of several years.
Technology
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Rhizosphere bioremediation and natural attenuation were applied in combination to clean
up — at a relatively low cost — a site with a wide range of contaminant concentrations. The
contaminated soil was amended to achieve fertility targets throughout the depth and area of
the plume. A variety of grasses and clovers were grown on the plume to enhance rhizosphere
bioremediation. The plant material, nutrients, and remediated soil of the surface layers were
mixed with the contaminants in deeper layers of soil to enhance bioremediation at levels
deeper than the root systems of the crops used for phytoremediation. The deepest level of
contaminated soils had low concentrations of fuel and were monitored to track natural
attenuation.
Benefits
• An innovative combination of land farming by removing the soil from the site and onsite remediation
made it possible to treat a wide range of contaminants.
• The mix of plants used for phytoremediation provided a robust crop with the added benefit of
converting an eyesore — a railroad yard — into a beautiful field that blooms several times each year.
• Operations and monitoring cost were lower than the costs of other alternatives.
Remediation of Wood Preservative Wastes Through Plant Cultivation
Union Pacific Railroad, Laramie, Wyoming
This 140 -acre site had been used to treat railroad ties with wood preservatives for nearly 100
years. An innovative pump and treat system composed of horizontal drain lines was used to
recover approximately 1.7 million gallons of mobile dense nonaqueous -phase liquid. As rates of
recovery declined, a long -term system for continued remedlation of residual contamination was
needed. Contaminants of concern included polycyclic aromatic hydrocarbons (PAHs) and
pentachlorophenol (PCP). CH2M HILL and Its subsidiary OMI are assisting the client with
permitting, planning, design, construction, and operation of a phytoremediation system for this
site, including irrigation. Plants to be used at the site include native cottonwood, willow, alfalfa,
and several grasses. Planting 50 acres of the site began in 1999, and will continue through
2001.
Technology
Rhizosphere bioremediation will be used to obtain continued reduction of contaminant
concentrations in the soil. Rhiozosphere bioremediation is the use of plant roots to enhance
microbiological degradation of organics such as PAH. Both trees and grasses will be established
and maintained in a state of vigorous growth through irrigation and soil amendments.
Benefits
• For a low cost, this system will provide tong -term continued reduction of soil contamination.
• The aesthetics of the site will be greatly improved by establishment of this plant -based system.
• Rhizosphere bioremediation will accelerate the natural breakdown of contaminants.
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• Educational and recreational opportunities will be enhanced because the phytoremediation system
will incorporate the extension of a planned bike path system for the city.
Residual Petroleum Waste Remediation Through Tree Cultivation
Weyerhaeuser
CH2M HILL worked with Weyerhaeuser to establish vegetation on the site of a former truck
maintenance facility. The soils at this site have elevated levels of BTEX (benzene, toluene,
ethylbenzene and xylenes) and TPH (total petroleum hydrocarbons) and have been compacted
from heavy truck traffic. Following extensive site preparation and addition of soil amendments
to ameliorate problems with soil compaction, acidity, and low fertility, alder trees were
established.
Technology
Nitrogen and phosphorus fertilization amendments were added to the soil to Improve tree
growth and to enhance natural attenuation and phytoremediation through rhizosphere
bioremediation.
Benefits
• The tree system will transform a highly disturbed site into a stable site beautified by plant growth and
supported by a natural ecosystem.
• The root system of hybrid poplars will enhance the ability of microorganisms in the soil to degrade
residual BTEX and TPH.
• Increased evapotranspiration will reduce the potential for contaminants to migrate beyond the
boundaries of the site.
Phytoremediation of Petroleum Hydrocarbons
Pacific Islands
CH2M HILL Is leading a three -year research and demonstration project investigating
phytoremediation of petroleum hydrocarbons using native plants in the Hawaiian Islands for
the U.S. Army Corps of Engineers. Partners in the study will include the University of Hawaii,
University of Iowa, USDA -ARS, and a Hawaiian botanical consulting firm. A greenhouse study
will be used to screen a variety of plant candidates, and the site of a former tank farm will be
used to establish replicated field plots. Protocols used In the field study will be similar to that
developed by the Remediation Technologies Development Forum (RTDF) subgroup on
phytoremediation of petroleum hydrocarbons in soils.
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Report: Phytoremediation in Oregon as a Pollution Control Tool,
prepared for the Oregon Department of Environmental Quality
CH2M HILL assisted the Oregon Department of Environmental Quality (DEQ) in the
development and preparation of a report that synthesizes information about the features,
feasibility, and usability of phytoremediation In Oregon as a pollution control tool. The research
was performed in conjunction with a similar effort being conducted by EPA Region 10.
The purpose of the report is to document the design and performance parameters currently
used for plant -based pollution treatment and remediation processes and make it available to
Oregon communities and industries, wastewater treatment engineers and designers, and DEQ
staff. To accomplish this CH2M HILL compiled a database of existing projects and evaluated the
approaches used for different types of waste, the lessons learned from the projects, benefits of
phytoremediation, and future data collection needs. The project data were also integrated Into
the national phytoremediation database developed by EPA headquarters.
Report: Guidance for Successful Phytoremediation
Center for Waste Reduction Technologies
Guidance for Successful Phytoremediation is a report designed to assist industrial site
managers in the evaluation of phytoremediation. The report focuses on the practical application
of phytoremediation technology, addressing the following topics:
• Definitions of technologies, typical applications, and fundamental processes involved
• Preliminary evaluation of phytoremediation as a site strategy
• Potential application by contaminant group
• Ecological risk and ecosystem modification
• Modeling approaches to predict performance
• Operations, maintenance, monitoring, and long -term site management
• Potential failure modes and contingencies
• Reid studies
• Economic considerations
The report was sponsored by the Center for Waste Reduction Technologies (CWRT), which is a
not -for -profit arm of the American Institute of Chemical Engineers. CH2M HILL prepared the
report with the assistance of representatives from participating chemical companies and
contributors and reviewers from several universities.
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