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I Garfield County Building & Planning Department 108 8th Street, Suite #401 Glenwood Springs, Co. 81601 Offlce:970·945·8212 Fax: 970·384-3470 Inspection Line: 970-384-5003 Building Permit No. \\\ '60 Parcel No: __ ___:2407-071-01-002 -- Locality: __ Horbetz Addit[gn, Lot 8 Job Address: _TBD CR 3Q1, Parachute~-~~--- Use of Building: ---~----._...ew __ a,.cte,_r f.-ilt__.ra_..ti-'-'on.-r...-.-.-fo_r ~To"'w,_n ..•. ~o_f _Pa.-r_ac_h.c.ut"'e·········-----· Owner: Town of Parachute Contractor: Fees: Plan Check: $ 254.31 Septic: -·--····---·-·-·-----~·-·"~'""-- Bldg Permit: 391.25 Other Fees: """" ····~~~~------···- Total Fees: $ 645.56 Clerk: ~-· Date: 1q I 0( I CfJ_ ___ I 5 6 7 12 GARFIELD COUNTY BUILDING PERMIT APPLICATION 108 gth Street, Suite 401, Glenwood Springs, Co 81601 Phone: 970-945-8212 I Fax: 970-384-3470 I lnspeetion Line: 970-384-5003 www. gar fie! d -county. com A It Ph: No. of Floors: / I Authority, This application for a Building Pennit must be signed by the Owner of the property, descl"ibed above, or an authorized agent. lfthe signan1re below is not that of the Owner, a separate letter of authority, signed by the Owner, must be provided with this Application. Legal Access. A Building Permit cannot be issued without proof of legal and adequate access to the property for purposes of inspections by the Building Department. Other Permits. Mul!ip!e separate permits may be required: ( l) State Electrical Pennit, (2) County JSDS Pennit, (3) another pem1it required for usc on thc property identified above, e.g. State or County Highway/ Road Access or a State Wastewater Discharge Pe11nit. Void Permit. A Building Permit becomes null and void if the work authorized is not commenced within 180 days of the date ofissnance and if work is suspended or abandoned for a period of 180 days after commencement CERTIFICATION I hereby certify that I have read this Application and that the information contained above is true and correct. I understand that the Building Department accepts the Application, along with the plans and specifications and other data submitted by me or on my behalf(submittals), based upon my ce1tification as to accuracy. Assuming completeness of the submittals and approval of this Application, a Building Pennit will be issued granting permission to me, as Owner, to construct the structure(s) and facilities detailed on the submittals reviewed by the Building Department. In consideration ofthe issuance oft he Building Pe11nit, I agree that I and my agents will comply with provisions of any federal, state or local law regulating the work and the Garfield County Building Code, ISDS regulations and applicable land use regulations (County Regulation(s)). I acknowledge that the Building Permit may be suspended or revoked, upon notice from the County, if the location, cons!Juction or use of the sttucture(s) and facility(ies), described above, are not in compliance with County Regulation(s) or any other applicable law. I hereby grant permission to the Building Department to enter the property, described above, to inspect the work. I further acknowledge that the issuance of the Building Permit does not prevent the Building Official fi"om: (I) requiring the correction of errors in the submittals, if any, discovered after issuance; or (2) stopping constmction or usc oft he structure(s) or facility(ies) if such is in violation f:~fCf~'"j'j'~[:~:~~~j]:~~;{jJ['~"j''~'~'~pp~l~lo~o~bl~ojlJ'w~~· ~:::~::::::::::::~:~~::::::::~~·: · submittals, and inspections ofthe work by the Building Dcpm1ment do not constihl!e an acceptance of responsibility or liability by the County of errors, omissions · for compliance with federal, state and local laws and County Regulations rest with me and my authmized agents, including without , CERTIFICATION ABOVE: STAFF USE ONLY Special Conditions: oKkv~VW'f'~ ~~ft~f(~~ W-.~ -. Adjusted Valuation: Plan Check Fee: Permit Fee: Manu home Fee: Mise Fees: £-4 /(2S.CXJ ~-SI -04l~~~ ~ ISDS Fee: ~tFees: V .gt)5'~~ 3~().~() BP No & Issue Date:,, ISDS No & Issued Date: -Lt5" Cr Setbacks: OCCGroup: ConstType: ~~b ---. B!,DGDEPT: v iDEP~ \~~~\~ tl/&/fJf; oL&!&Pl . :,.._~~~~!'\ APPROVAL ' DATE ' APPROVAL DATE ·· .. . .· . ' The following items are required by Garfield County for a final Inspection: I) A final Electrical Inspection from the Colorado State Electrical Inspector. 2) Permanent address assigned by Garfield County Building Department and posted at the structure and where readily visible from access road. 3) A finished roof; a lockable building; completed exterior siding; exterior doors and windows installed; a complete kitchen with cabinets, sink with hot & cold running water, non-absorbent kitchen floor covering, counter tops and finished walls, ready for stove and refrigerator; all necessary plumbing. 4) All bathrooms must be complete, with washbowl, tub or shower, toilet, hot and cold running water, non-absorbent floors, walls finished, and privacy door. 5) Steps over three (3) risers, outside or inside must be must have handrails. Balconies and decks over 30" high must be constructed to all IBC and IRC requirements including guardrails. 6) Outside grading completed so that water slopes away from the building; 7) Exceptions to the outside steps, decks, grading may be made upon the demonstration of extenuating circumstances., i.e. weather. Under such circumstances A Certificate of Occupancy may be issued conditionally. 8) A final inspection sign off by the Garfield County Road & Bridge Department for driveway installation, where applicable; as well as any final sign off by the Fire District, and/or State Agencies where applicable. A CERTIFICATE OF OCCUPANCY (C.O.) WILL NOT BE ISSUED UNTIL ALL THE ABOVE ITEMS HAVE BEEN COMPLETED. A C.O. MAY TAKE UP TO 5 BUSINESS DAYS TO BE PROCESSED AND ISSUED. OWNER CANNOT OCCUPY OR USE DWELLING UNTIL A C.O. IS ISSUED. OCCUPANCY OR USE OF DWELLING WITHOUT A C.O. WILL BE CONSIDERED AN ILLEGAL OCCUPANCY AND MAY BE GROUNDS FOR VACATING PREMISES UNTIL ABOVE CONDITIONS ARE MET. I understand and agree to abide by the above conditions for occupancy, use and the issuance of a C.O. for the building identified in the Building Permit. DATE VALUATION FEE DETERMINATION Applicant Address Date .,;T='o"'wn~oc-;fP:-'arac=::,:h:::ut:::;:e _______ Subdivision ~TB~D:,.,, C'Coc.R.~30~1:._ ________ Lot/Block 11/6/2008 Contractor Finished (Livable Area): Main Upper Lower Other Total Basement: Unfinished Square Feet Valuation Conversion of Unfinished to Finished Total Valuation Garage: Carport: Total Valuation Crawl Space Total Valuation Decks/ Patios Covered Open Total Valuation Type of Construction: Occupancy: Valuation Total Valnation sq.ft sq.ft sq.ft sq.ft X $74.68 0 sq.lt sq.ft X $41.00 sq.ft X $33.68 Commercial sq.ft X $18.00 sq.ft X $12.00 sq.ftX $9.00 sq.ft X $24.00 sq.ft X $12.00 625 sf X $39.88 sf X sf X sf X sf X sf X Horbetz Lot8 0.00 0.00 0.00 0.00 0.00 24,925.00 24,925.00 GARFIELD COUNTY BUILDING AND PLANNING 970-945-8212 MINIMUM APPLICATION REQUIREMENTS FOR CONSTRUCTION OF COMMERCIALORMULTI-FAMILYRESIDENTIALBUILDINGS Including NEW CONSTRUCTION ADDITIONS ALTERATIONS And MOVED BUILDINGS In order to understand the scope ofthe work intended under a permit application and expedite the issuance of a permit it is important that complete information be provided. When reviewing a plan and it's discovered that required information has not been provided by the applicant, this will result in the delay of the permit issuance and in proceeding with building construction. The owner or contractor shall be required to provide this information before the plan review can proceed. Other plans that are in line for review may be given attention before the new information may be reviewed after it has been provided to the Building Department. Please review this document to determine if you have enough information to design your project and provide adequate information to facilitate a plan review. Also, please consider using a design professional for assistance in your design and a construction professional for construction of your project. Any project with more than ten (10) occupants requires the plans to be sealed by a Colorado Registered Design Professional. To provide for a more understandable plan and in order to determine compliance with the building, plumbing and mechanical codes, applicants are requested to review the following checklist prior to and during design. Plans to be included for a Building Permit must be on draft paper at least 18"x 24"" and drawn to scale. Plans must include a floor plan, a concrete footing and foundation plan, elevations all sides with decks, balcony steps, hand rails and guard rails, windows and doors, including the fini~h grade and original grade 1 line. A section showing in detail, from the bottom of the footing to the top of the roof, including re-bar, anchor bolts, pressure treated plates, floor joists, wall studs and spacing, insulation, sheeting, house-rap, (which is required), siding or any approved building material. Engineered foundations may be required. Check with the Building Department. A window schedule. A door schedule. A floor framing plan, a roofing framing plan, roof must be designed to withstand a 40 pound per square foot up to 7,000 feet in elevation, a 90 M.P.H. windspeed, wind exposure B or C, and a 36 inch frost depth. All sheets need to be identified by number and indexed. All of the above requirements must be met or your plans will be returned. All plans submitted must be incompliance with the 2003 IBC, IPC, IMC, IFGC, and IFC. Applicants are required to indicate appropriately and to submit completed checklist at time of application for a permit: 1. Is a site plan included that identifies the location of the proposed structure, additions or other buildings, setback easements, and utility easements showing distances to the property lines from each comer of the proposed structure prepared by a licensed surveyor and has the surveyors signature and professional stamp on the drawing? Slopes of 30% or more on properties must be show on site plan. (NOTE: Section 106.2) Any site plan for the placement of any portion of a structure within 50 ft. of a property line and not within a previously surveyed building envelope on a subdivision final plat shall be prepared by a licensed surveyor and have the surveyors signature and professional stamp on the drawing. Any structure to be built within a building envelope of a lot shown on a recorded subdivision plat, shall include a copy of the building envelope as it is shown on the final plat with the proposed structure located within the envelope. Yes ._...../ 2. Does the site plan when applicable include the location of the I.S.D.S. (Individual Sewage Disposal System) and distances to the property lines, wells (on subject property and adjacent properties), streams or water courses? This information must be certified by a licensed surveyor with their signature and professional stamp on the design. Yes __..---Not necessary for this project __ _ 3. Does the site plan indicate the location and direction of the State, County or private road accessing the property? Yes__dl!J 4. Is the I.S.D.S. (Individual Sewage Disposal System) designed, stamped and signed by a Colorado Registered Engineer? Yes. / Not necessary for this project. __ _ 2 5. Are the plans submitted for application review construction drawings and not drawings that are stamped or marked identifying them as ''Not for construction, for permit issuance only", "Approval drawings only", "For permit issuance only" or similar language? Yes / Not necessary for this project:__ __ 6. Do the plans include a foundation plan indicating the size, location and spacing of all reinforcing steel in accordance with the building code or per stamped engineered design? Yes__::::::::__ Not necessary for this project __ 7. If the building is a pre-engineered structure, is there a stamped, signed engineered foundation plan for this building? Yes~ Not necessary for this project __ 8. Do the plans indicate the location and size of ventilation openings for under floor crawl spaces and the clearances required between wood and earth? Yes__::::::__ Not necessary for project __ 9. Do the plans indicate the size and location of the ventilation openings for the attic, roof joist spaces and soffits? Yes__:::::::__ Not necessary for this project __ 10. Do the plans include design loads as required under the IBC or IRC for roof snow loads, (a minimum of 40 pounds per square foot in Garfield County)? Yes__:::::::__ Not necessary for this project __ 11. Do the plans include design loads as required for floor loads under the IBC or IRC? Yes__:::::::_ Not necessary for this project __ 12. Does the plan include a building section drawing indicating foundation, wall, floor, and roof construction? Yes~ Not necessary for this project __ 13. Is the wind speed and exposure design included in the plan? Yes~ Not necessary for this project __ . 14. Does the building section drawing include size and spacing of floor joists, wall studs, ceiling joists, roof rafters or joists or trusses? Yes __ Not necessary for this project ..--- 3 15. Does the building section drawing or other detail include the method of positive connection of all columns and beams? Yes __ Not necessary for this project~ 16. Does the elevation plan indicate the height of the building or proposed addition from the undisturbed grade to the midpoint between the ridge and eave of a gable or shed roof or the top of a flat roof? (Check applicable zone district for building height maximum) Yes __ Not necessary for this project __ / 17. Does the plan include any stove or zero clearance fireplace planned for installation including make and model and Colorado Phase II certifications o;jhase II EPA certification? Yes __ Not necessary for this project __ 18. Does the plan include a masonry fireplace including a fireplace section indicating design to comply with the IBC or IRC? / Yes __ Not necessary for this project __ 19. Does the plan include a window schedule or other verification that egress/rescue windows from sleeping rooms and/or basements comply with the r,:9Jlirements of thte IBC or IRC? Yes __ Not necessary for this project __ 20. Does the plan include a window schedule or other verification that windows provide natural light and ventila~for all habitable rooms? Yes __ Not necessary for this project __ 21. Do the plans indicate the location of glazing subject to human impact such as glass doors, glazing immediately adjacent to such doors; glazing adjacent to any surface normally used as a walking surface; sliding glass doors; fixed glass panels; shower doors and tub enclosures and specify safety glazi~ these areas? Yes Not necessary for this project / 22. Do the plans include a complete design for all mechanical systems planned for installation in this building? Yes /No Not necessary for this project __ _ 4 23. Have all areas in the building been accurately identified for the intended use? (Occupancy as identified in the IBC Chapter 3) Yes / Not necessary for this project. __ _ 24. Does the plan indicate the quantity, form, use and storage of any hazardous materials that may be in use in this building? Yes ,......----Not necessary for this project __ 25. Is the location of all natural and liquid petroleum gas furnaces, boilers and water heaters indicated on the plan? Yes~ Not necessary for this project __ 26. Do the plans indicate the location and dimension of restroom facilities and if more than four employees and both sexes Jlre employed, facilities for both sexes? Y es __ v-_ 1\. Nl ot necessary for this project __ 27. Do the plansjndicate that restrooms and access to the building are handicapped accessible? Yes_/_ Not necessary for this project __ 28. Have two (2) somplete sets of construction drawings been submitted with the application? Yes __ /_ 29. Have you designed or had this plan designed while considering building and other construction code requirements? Yes v 30. Does the plan accurately indicate what you intend to construct and what will receive a final inspection by the Ga~d County Building Department? Yes __ 31. Do your plans comply with all zoning rules and regulations in the County related to your zone district? For comer l~e supplemental section 5.05.03 in the Garfield County Zoning Resolution for setbacks. Yes __ _ 32. Do you understand that approval for design and/or construction changes are required prior to the implementation ofthese changes? Yes· / 5 33. Do you understand that the Building Department will collect a "Plan Review" fee from you at the time of application and that you will be required to pay the "Permit" fee as well as any "Septic System" or "Road ryct" fees required, at the time you pick up your building permit? Yes 34. Are you aware that you are required to call for all inspections required under the IBC including approval on a final inspection prior to receiving a Certificate of Occupancy and occupancy of the building? Yes / 35. Are you aware that the Permit Application must be signed by the Owner or a written authority be given for an Agent and that the party responsible for the project must comply with the Uniform Codes? Yes / -- 36. Are you aware that you must call in for an inspection by 3:30 the business day before the requested inspection in order to receive it the following business day? Inspections will be made between 7:30a.m. and 3:30p.m. Monday through Friday. Inspections are to be called in to 384-5003. Yes / -- 3 7. Are you aware that requesting inspections on work that is not ready or not accessible will result in a $50.00 re-inspection fee? Yes~ 38. Are you aware that prior to submittal of a building permit application you are required to show proof of a legal and adequate access to the site? This may include (but is not limited to) proof of your right to use a private easement/right of way; a County Road and Bridge permit; a Colorado Dept. of Highway Permit including a Notice to Proceed; a permit from the federal government or any combination. You can contact the Road & Bridge Department at 625-8601. See Phone book for other agencies Yes / -- 39. Do you understand that you will be required to hire a State of Colorado Licensed Electrician and Plumber to perform installations and hookups? The license number will be required at time of inspection. Yes--=::::::_ 40. Are you aware, that on the front of the building permit application you will need to fill in the Parcell Schedule Number for the lot you are applying for this permit on prior to submittal of the building permit application? Your attention in this is appreciated. Yes / 41. Do you know that the local fire district may require you to submit plans for their review of fire safety issues? Yes~ (Please check with the building department about this requirement) 6 42. Do you understand that if you are planning on doing any excavating or grading to the property prior to issuance of a building permit that you will be required to obtain a grading permit? Yes . / Not necessary for this project __ 43. Did an Architect seal the plans for your commercial project? State Law requires any commercial project with occupancy of more than 10 persons as per Section 1004 of the IBC to prepare the plans and specifications for the project. Yes __ Not Necessary for this project /' I hereby acknowledge that I have read, understand, and answered these questions to the best of my ability. Signature ' Date _________ .(evenings) Phone: '170-2 7JS-Z&J" (days); Project Name: 13.._9 -£~I±.,. ... b o""".S<f!!. Project Address:_~? _____________ _ Note: On any of these questions you may be required to provide this information. If required information is not supplied, delays in issuing the permit are to be expected. Work may not proceed without the issuance of the permit. *If you have answered "Not necessary for this project" on any of the questions and it is determined by the Building Official that the information is necessary to review the application and plans to determine minimum compliance with the adopted codes, please expect the following: A. The application may be placed behind more recent applications for building permits in the review process and not reviewed until required information has been provided and the application rotates again to first position for review. B. Delay in issuance of the permit. C. Delay in proceeding with construction. BpcommDec2007 7 .. GARFIELD COUNTY BUILDING REQUIREMENTS Codes: 2003 IRC, IBC, IFGC, IMC, IPC, Setbacks: Check subdivisions and zone district for setback requirements. Snowload (measured at the roof): 40PSF up to 7000ft. elevation. 50PSF 7001 to 8000ft. 75PSF 8001 to 9000ft. lOOP SF 9001 to lOOOOft. Seismic design category: B Weathering probability for concrete: Severe Termite infestation probability: None to slight Wind speed: 90mph Decay probability: None to slight Wind Exposure: B or C (see section R301.2.1.4) Frost Depth: 36in. to 8000ft. elevation. 42in. 8001 and above. Winter Design Temperature: Minus 2 to 7000ft.; minus 16 over 7000ft. elevation. Air Freezing Index: 2500deg F-days to 7000ft.; over 7000ft. to be determined by Building Official. Ice shield under-layment required. Mean Annual temp.: Variable Insulation: Maximum glazing U factor: 0.50 Minimum R-Values: • Ceilingsfroofs R values are: R-30 stick built structures. R-38 Jog construction and steel rafter construction. • Walls R values are R-19 wood frame; R-19 cavity R-3 sheathing steel studs. • Floors R-values are R-19. ·• Basement wall R-values are R-10 beTow · grade, R-19 above grade. • Slab perimeter R-value and depth is R- 10/36in. • Crawl space wall R-values are R-IO below grade and R-19 above grade If floors over crawl spaces are not insulated, the crawl space walls must be insulated. Basement wall must be insulated to frost depth. Common walls garage to house must have R -19 insulation. Common ceiling/floor garage to house must have R-19. Take precautions to protect plumbing in these areas. N 11180 o. ----------~~~---Assessor's Parcel No. 2407-071-01-002 Date 11/19/2008 I z tJ . BUILDING PERMIT CARD . Jon Address CR 301, Parachute I Horbetz Addition, Lot 8 Owner _______ T._o'-'w"-n'--'-o._f ._Pa:ccr_a_ch:__u_t_e _________ Address PO Box 100, P'chute Phone # 970-285-7630 Contractor _____ M_o_r-_st~o_ra-'g=-e--~-------Address __ 3_0_1_0_1_-7_0_B_;_,_G_J ______ Phone #970-254-0460 Setbacks: Front Rear------RH, _____ LH _____ Zoning 970-986-1821 (Mark) water filtration plant f/Town of P'chute Soils Test------------ Footing-~---------- Foundation __________ _ Grout ________________ _ Underground Plumbing------- Rough PI umbi ng =----:-;:;;;--::c.---- Framing 2-LK-o 7 st:_JV. Insulation z-;;;-o '? <J;?0I. Roofing------------ Drywall ------------ Gas Piping---------------- DATE INSPECTIONS NOTES Weatherproofing ___________ _ Mechanical _____________ _ Electrical Rough (State)--------- Electrical Final (State) _______ --=-_ Final ;2. ·11!-1.? /Checklist Completed? :W?t1-- Certificate Occupancy # ---------Date ___________ _ Septic System # ------------ Date------------Final ___________ _ Other ______________ ___ (continue on back) PERMIT NO. COUNTY OF GARFIELD -BUILDING DEPARTMENT CORRECTION NOTICE 1 08 8th St., Suite 401 Glenwood Springs, Colorado Phone (970) 945-8212 Job located at /Z Cl C I( '30 / Permit No. .//Iff 0 I have this day inspected this structure and these premises and found the following corrections needed: ---- You are hereby notified that the above correction must be inspected before covering. When correction(s) have been made, call for inspection at 970-384-5003. Date -z--/P 20 e 7 " Building Inspector --~C=7~ .. ~;;:::· cl~~~~_?:.~-:::t:e_~~&~~~:::::::?:c::::::- Phone (970) 945-8212 7 Addendum to Building Permit for Revell Springs (Town of Parachute) Filtration Building Prepared by Filter Tech Systems 04 November 2008 The following chemicals will be stored on site: Aluminum Chlorhydrate (SummaChlor 50) Sodium Hypo-Chlorite-12% Sulfuric Acid Sodium Hydroxide The chemicals will be delivered and used out of 55-gallon drums and stored on the 8- drum spill platform. The maximum amount of chemicals for each type would be one full 55-gallon drum plus a small amount (5-10 gallons) remaining in the drum being used. Attached are MSDS sheets for the chemicals being used and a cut sheet for the drum platform. If there is any other information required to complete the permit process, please contact Deb@FilterTechSystems.com or call Filter Tech at 970-254-2855 Polyethylene Drum Platforms Drum platforms are made of polyethylene for excellent chemical restistance. They are forkliftable and. have 3/4" drain plugs. Grating has 1-3/4" square openings and removes easily for cleaning. Meets EPA requirements for secondary spill containment of hazardous materials ( 40 CFR 264.17 5). Model2320 8-Drum Platform 90 Gallon Sump Capacity 102" X 51-1/2" X 6-1/2" %Aluminum 12.1 -12.7 %Ai203 23.0-24.0 %Chloride 7.9-8.4 AI:CI Molar Ratio 1.90:1-2.10:1 pH (15% aqueous) 4.0-4.4 Specific Gravity @ 15°C 1 .330 - 1 .350 Odor Characteristic Appearance Clear, colorless liquid %Basicity 82-85 (Sumalchlor 50 is NSF approved up to 250 mg/L) Uses Summit Research Labs' Sumalchlor 50 is used with exceptional performance results in numerous industrial and municipal water, wastewater, and process applications. Developed as a proprietary polyinorganic formulation, Sumalchlor 50 is manufactured under extremely rigorous standards using only the highest quality raw materials to produce a consistent product that is both exceptionally pure and highly stable. Sumalchlor 50 has particularly low levels of sulfate, iron, and other objectionable metal impurities. Storage & Handling Store Sumalchlor 50 at moderate temperatures and protect from freezing. If frozen, thaw and mix thoroughly prior to use. Summit recommends using corrosion-resistant materials such as PVC/CPVC, polyethylene, polysulfone, fiberglass-lined, or other plastic-lined material for storage and feed systems. Avoid using unlined mild steel, stainless steel, copper, and aluminum metallurgy and their alloys in selecting tanks, piping, and wetted surfaces of pumps to feed the product. Standard Packaging For customer convenience, Summit's Sumalchlor 50 is available in 55 gallon drums (600 lbs./272.7 kg.), totes (3000 lbs./1363.6 kg.), tank wagons and rail cars. SUMMIT Summit Research Labs 45 River Road, Suite 300 Flemington, New Jersey 08822 USA Phone: (908)782-9500 Fax: (908)782-5377 E-mail: info@summitresearchlabs.com Web: www.summitresearchlabs.com SUMMIT RESEARCH LABS-HUGUENOT DIVISION MATERIAL SAFETY DATA SHEET MATERIAL NAME: SUMALCHLOR 50 EMERGENCY TELEPHONE NUMBER: (845) 856-5261 SECTION I-GENERAL INFORMATION MANUFACTURER'S NAME: SUMMIT RESEARCH LABS -HUGUENOT DIVISION ADDRESS: 15 BIG POND ROAD P.O.BOXF HUGUENOT, NEW YORK 12746-0626 PRODUCT AND TECHNICAL INFORMATION NUMBER: (908) 782-9500 PROPER SHIPPING NAME ( 49CFR 172.10 I): NONE D.O.T. HAZARD NAME (49CFR 172.101): NONE D.O.T. IDNUMBER(49CFR 172.IOI): NONE D.O.T. HAZARD CLASS (49CFR 172.101): NONE RCRA HAZARD CLASS (40CFR 261) (IF DISCARDED): NONE E.P.A. PRIORITY POLLUTANTS (40CFR 122.53): NONE HEALTH (NFPA): 2 FLAMMABILITY (NFPA): 0 REACTIVITY (NFPA): 0 NSF NAME: SUMALCHLOR 50 MAXIMUM USE OF PRODUCT IN POTABLE WATER IS 250 mg/L DESCRIPTION: PROPRIETARY BLEND SECTION 2-HAZARDOUS INGREDIENTS AS DEFINED IN 29 CFR 1910.1200 EXPOSURE LIMITS Page 1 of3 CAS NO. PROPRIETARY INGREDIENT CONTAINS WATER SOLUBLE ALUMINUM COMPOUNDS OSHA PEL! ACGIH TL V FOR ALUMINUM SOLUBLE SALTS: TWA 2 Mg/M3 AS ALUMINUM. SECTION 2A-AQUATIC TOXICITY SPECIES LC50/HRS PIMELPHALES PROMELAS 1056 mg/L/24hrs 832 mg/L/48hrs 684 mg/L/72hrs 609 mg/L/96hrs DAPHNIA MAGNA 642 mg/L/24hrs 397mg/L/48hrs SECTION 3 -EFFECTS OF OVEREXPOSURE EYE: DIRECT CONTACT IRRITATES SLIGHTLY TO MOD ERA TEL Y WITH REDNESS AND SWELLING. SKIN: A SINGLE RELATIVELY SHORT EXPOSURE CAUSES NO KNOWN ADVERSE EFFECT. REPEATED EXPOSURES MAY IRRITATE. INHALATION: INHALING DUST OR MIST CREATED DURING USE MAY INJURE THE RESPIRATORY SYSTEM AND CAUSE AN ADVERSE LUNG REACTION. ORAL: SMALL AMOUNTS TRANSFERRED TO THE MOUTH BY FINGERS DURING USE, ETC., SHOULD NOT INJURE. SWALLOWING LARGE AMOUNTS MAY CAUSE INJURY. COMMENTS: THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. SECTION 4 -EMERGENCY AND FIRST AID PROCEDURES EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: WIPE OFF AND FLUSH WITH WATER, THEN WASH WITH SOAP AND WATER. INHALATION: GET MEDICAL ATTENTION IF THERE IS ANY DISCOMPORT. ORAL: GET MEDICAL ATTENTION IF LARGE AMOUNTS SWALLOWED OR THERE IS ANY DISCOMFORT. SUMMIT RESEARCH LABS-HUGUENOT DIVISION MATERIAL SAFETY DATA SHEET MATERIAL NAME: SUMALCHLOR 50 SECTION 5-FIRE AND EXPLOSION DATA FLASH POINT (METHOD USED): NONE, NOT FLAMMABLE EXTINGUISHING MEDIA: COOL CONTAINERS WITH WATER FOG. Page 2 of3 SPECIAL FIRE FIGHTING PROCEDURES: SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING CHEMICALS. UNUSUAL FIRE AND EXPLOSION HAZARDS: HAZARDOUS CHLORINE COMPOUNDS MAY FORM WHEN EXPOSED TO FIRE OR HIGH HEAT. SECTION 6-PHYSICAL DATA BOILING POINT (AT 760 MM HG): APPROX. 212F/IOOC SPECIFIC GRAVITY (AT 77 DEG F/25 DEG C): 1.34 MELTING POINT: APPROX. 32F/OC VAPOR PRESSURE (AT 77 DEG F/25 DEG C): 24 MM (WATER) VAPOR DENSITY (AIR~ I AT 77 DEG F/25 DEG C): THAT OF MOIST AIR PERCENT VOLATILE BY WEIGHT(%): SO% (WATER) EVAPORATION RATE: AS WATER SOLUBILITY IN WATER(%): APPROX. 100 ODOR, APPEARANCE, COLOR: NO ODOR, LIQUID, CLEAR AND COLORLESS. NOTE: THE ABOVE INFORMATION IS NOT INTENDED FOR USE IN PREPARING PRODUCT SPECIFICATIONS. CONTACT MANUFACTURER BEFORE WRITING SPECIFICATIONS. SECTION 7-REACTIVITY DATA STABILITY: STABLE INCOMPATIBILITY (MATERIAL TO A VOID): OXIDIZING MATERIAL CAN CAUSE A REACTION. CAUSTICS WILL PRECIPITATE ALUMINUM HYDROXIDE. CONDITIONS TO A VOID: EXPOSURE TO ABOVE AND CONTINUOUS I-IIGH TEMPERATURES. HAZARDOUS DECOMPOSITION PRODUCTS: CHLORINE COMPOUNDS, METAL OXIDES. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR SECTION 8-SPILL, LEAK, MAINTENANCE /REPAIR AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN. WASH WITH CLEARWATER ONLY. PERSONAL PROTECTIVE EQUIPMENT: EYES: SAFETY GLASSES, AS A MINIMUM, GOGGLES IF SPLASHING COULD OCCUR. SKIN: WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE. JNHALA TION: NO RESPIRATORY PROTECTION SHOULD BE NEEDED. WASTE DISPOSAL METHOD: MANUFACTURER SUGGESTS THAT ALL LOCAL, STATE, AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION BE REVIEWED TO DETERMINE APPROVED DISPOSAL PROCEDURES. CONTACT MANUFACTURER IF THERE ARE ANY DISPOSAL QUESTIONS. D.O.T. (49CFR 171.8)/E.P.A. (40CFR 117) SPILL REPORTING INFORMATION: HAZARDOUS SUBSTANCE: NONE REPORTABLE QUANTITY: NOT APPLICABLE CON CENTRA TJON OF HAZARDOUS SUBSTANCE: NOT APPLICABLE. REPORTABLE QUANTITY OF PRODUCT: NOT APPLICABLE. SEE SEC. 1 I FOR ADDITIONAL SARA COMPLIANCE INFORMATION. 2 SUMMIT RESEARCH LABS -HUGUENOT DIVISION MATERIAL SAFETY DATA SHEET MATERIAL NAME: SUMALCHLOR 50 SECTION 9-ROUTINE HANDLING PRECAUTIONS PERSONAL PROTECTIVE EQUIPMENT: EYES: SAFETY GLASSES, AS A MINIMUM. GOGGLES IF SPLASHING COULD OCCUR. SKIN*: W ASH!NG AT MEALTIME AND END OF SHIFT IS ADEQUATE. Page 3 of3 INHALATION: NO RESPIRATORY PROTECTION SHOULD BE NEEDED UNLESS MISTS ARE CREATED. VENTILATION: LOCAL EXHAUST: NONE SHOULD BE NEEDED. GENERAL VENTILATION RECOMMENDED. SUITABLE RESPIRATOR: DUST/MIST TYPE. THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING. USE AT ELEVATED TEMPERATURES, OR AEROSOLISPRA Y APPLICATIONS MAY REQUIRE ADDED PRECAUTIONS. *GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. COMMENTS: AVOID EYE CONTACT. SECTION 10-SPECIAL PRECAUTIONS USE REASONABLE CARE AND CAUTION IN HANDLING AND STORAGE. STORE BETWEEN 32F/OC AND 120F/49C. SECTION II -COMMENTS ADDITIONAL SARA REGULATORY COMPLIANCE INFORMATION SEC. 312 HAZARD CLASS: IMMEDIATE AND DELAYED. SEC. 313 NOTIFICA T!ON: NOT APPLICABLE; EITHER NONE PRESENT OR NONE PRESENT IN REGULATED QUANTITIES. THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES, NOT AS PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE. ALL COMPONENTS OF TillS PRODUCT ARE ON THE FOLLOWING INVENTORIES: US TSCA; CANADA DSL; EUROPE E!NECS PREPARED BY: JOHN KRUPUN!CH Filecode: S50 DATE: l5JULY2002 3 Health 3 Science Lab Fire ~ ,~0~ Chemicals & Laboratory Equipment ~~~hl.vity;: .o Personal Protection Material Safety Data Sheet Sodium Hypochlorite, 5% MSDS Section1 :· Cn¢lt1ical. Product 'and ·.qofilpany.·Jdentific;!ltion·'-·- Product Name: Sodium Hypochlorite, 5% Catalog Codes: SLS1654 CAS#: Mixture. RTECS: Not applicable. TSCA: TSCA 8(b) inventory: Sodium hypochlorite; Sodium hydroxide; Water Cl#: Not applicable. Synonym: Chlorine Bleach, Bleach, Soda Bleach, Chlorox; Sodium Hypochlorite, Solution, 5% Available Chlorine Chemical Name: Hypochlorous acid, sodium salt, solution Chemical Formula: Not applicable . Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901·7247 International Sales: 1-281-441-4400 Order Online: ScienceLab.com CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non-emergency assistance, call: 1-281-441-4400 [·•·-•-'••·'_ .•. ,. ;c'·····:· • s~chon:2: c()filpositlonandlnforfilation on. Ingredients. ,. ,,_.f)::.-..... _ •• _ .. , ....... , •. -.. ·.:.-.• <,._ .. _,,_ •... _._ Composition: Name CAS# %by Weight Sodium hypochlorite 7681-52-9 4-7 ----------------------------------~-------------------------~--------------~ Sodium hydroxide 1310-73-2 <1 Water 7732-18-5 >92 Toxicological Data on Ingredients: Sodium hypochlorite: ORAL (LD50): Acute: 5800 mg/kg [Mouse]. 8910 mg/kg [Rat]. Section 3: Hazards Identification Potential Acute Health Effects: Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact (corrosive). Slightly hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. p. 1 Potential Chronic Health Effects: Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Sodium hypochlorite]. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. [Sodium hypochlorite]. Mutagenic for mammalian somatic cells. [Sodium hydroxide]. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to lungs, mucous membranes, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. · Section''4: .Finif AiqMeitsllresi···· Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used .Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Serious Ingestion: Not available. ! ··•· ·•· . · •. · ·.· ·. · .. · ·• •·.·. · ···:· ·•· .• · .. •··.• Section 5: Fire andExplosion Data · ··•· · .. · · · .·: ........ ·· ... · •· ·. · • ·.· .•. · .. ··.·•···. • •· · •.. Flammability of the Product: Non-flammable. Auto-Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: combustible materials, metals, organic materials Explosion Hazards in Presence of Various Substances: Slightly explosive in presence of open flames and sparks. p.2 Non-explosive in presence of shocks. Fire Fighting Media and Instructions: Not applicable. Special Remarks on Fire Hazards: Releases chlorine when heated above 35 deg. C. The substance itself is non-combustible and does not burn. However, when heated to decomposition it emits corrosive and/or toxic fumes. May ignite combustibles. Fire risk in contact with organic materials. Contact with metals may evolve flammable hydrogen gas. Special Remarks on Explosion Hazards: Anydrous Sodium Hypochlorite is very explosive. Primary amines and calcium hypochlorite or sodium hypochlorite react to form normal chloroamines, which are explosive. Interaction of ethyleneimine with sodium (or other) hypochlorite gives the explosive N-chloro cmpd. Removal of formic acid from industrial waste streams with sodium hypochlorite soln becomes explosive at 55 deg c. Several explosions involving methanol and sodium hypochlorite were attributed to formation of methyl hypochlorite, especially in presence of acid or other esterification catalyst. Use of sodium hypochlorite soln to destroy acidified benzyl cyanide residues caused a violent explosion, thought to have been due to formation of nitrogen trichloride. (Sodium hypochlorite) Small Spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. large Spill: Corrosive liquid. Oxidizing material. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Avoid contact with a combustible material (wood, paper, oil, clothing ... ). Keep substance damp using water spray. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities . . ·. S~C:tlon·.7:Hai1CI1.ingand •St6rag~ Precautions: Keep locked up .. Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals, acids. Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agents and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers. Air Sensitive Sensitive to light. Store in light-resistant containers. ••••••• ••••••• .. •· .. · ... Section. 8: Exposure ColltrolsiPersonal Protecti<:>rt• , .. , ... ···•·••· .,.,,···.·•···•··· ... < i ·••···. •···· Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. p.3 . Personal Protection: Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Sodium hypochlorite TWA: 1 CEIL: 1 (ppm as C12) STEL: 1 (ppm as Cl2) from ACGIH (TLV) [United States] Sodium hydroxide STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/m3) from NJOSH Consult local authorities for acceptable exposure limits. ···••·•.•.•. ··••·· ··•·•····· ····:.·:: <: .•......•••. •·••··•·•··· •.··•······•·•·•.•.·.· •. Se.ctiori 9: F'hysicalan(f Chemical Properties ''··•·•········•·•····· '" ' •···············••·.•···.·.•···· <•• Physical state and appearance: Liquid. Odor: Characteristic. Chlorine-like (Slight.) Taste: Not available. Molecular Weight: Not applicable. Color: Colorless to light greenish yellow pH (1% soln/water): Neutral. Boiling Point: Decomposition temperature: 40"C (104"F) Melting Point: Not available. Critical Temperature: Not available. Specific Gravity: 1.07-1.093 (Water= 1) Vapor Pressure: 2.3 kPa (@ 20"C) Vapor Density: The highest known value is 0.62 (Air= 1) (Water). Volatility: Not available. Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available. lonicity (in Water): Not available. Dispersion Properties: See solubility in water. Solubility: Easily soluble in cold water. Section 10.: Stability.and Reactivity Data Stability: The product is stable. p.4 Instability Temperature: Not available. Conditions of Instability: Incompatible materials. light, air, heat Incompatibility with various substances: Reactive with reducing agents, combustible materials, organic materials, metals, acids. Corrosivity: Extremely corrosive in presence of aluminum. Corrosive in presence of stainless steel(304), of stainless steel{316). Non-corrosive in presence of glass. Special Remarks on Reactivity: Decomposed by carbon dioxide from air. Slowly decomposes on contact with air. Unstable in air unless mixed with sodium hydroxide. Incompatible with ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium phosphate. Decompostion of sodium hypochlorite takes place within a few seconds with these salts. Also incompatible with primary amines, phenyl acetonitrile, ethyleneimine, methanol, acidified benzyl cyanide, formic acid, urea, nitro compounds, methylscellulose, celloluse, aziridine, ether, ammonia. Mixing this product with chemicals (e.g. ammonia, acids, detergents, etc.) or organic matter (e.g. urine, feces, etc.) will release chlorine gas. Chloramine gas may be evolved when ammonia and bleach are mixed. Decomposed by hot water. Sensitive to light. Exposure to light accelerates decompositon. Special Remarks on Corrosivity: Sodium Hypochlorite is extremely corrosive to brass, and moderately corrosive to bronze. There is no corrosivity information for copper. Polymerization: Will not occur. ·· •... • .. ·sectiol111: roxicologh::allrit9rr)'latioll •··· Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals: Acute oral toxicity (LD50): 5800 mg/kg [Mouse]. (Sodium hypochlorite). Chronic Effects on Humans: CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by !ARC [Sodium hypochlorite]. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. [Sodium hypochlorite]. Mutagenic for mammalian somatic cells. [Sodium hydroxide]. Contains material which may cause damage to the following organs: lungs, mucous membranes, skin, eyes. Other Toxic Effects on Humans: Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact (corrosive). Slightly hazardous in case of inhalation {lung sensitizer, lung corrosive). Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic) (Sodium hypochlorite) Special Remarks on other Toxic Effects on Humans: Potential Health Effects: Can cause severe irritation and possible burns to skin and eyes. Eye contact may also cause corneal and conjunctival edema, conjunctival hemorrhages. Contact with skin may also cause vesicular eruptions and eczematoid dermatitis which becomes evident upon re-exposure. Prolonged or repeated eye contact may cause conjunctivitis. Ingestion can cause burns to the digestive tract. Symptoms may include: 1. pain and inflammation of the p. 5 mouth, pharynx, esophagus, and stomach, 2. erosion of the mucous membranes (chiefly of the stomach), nausea, vomiting, choking, coughing, hemorrhage, 3. circulatory collapse with cold and clammy skin (due to methemoglobinemia), cyanosis, and shallow respirations, 4. confusion, delirium, coma, 5. edema of the pharynx, glottis, larynx with stridor and obstruction, 6. perforation of the esophagus, or stomach, with mediastinitis or peritonitis. Inhalation causes slight to severe respiratory tract irritation and delayed pulmonary edema. Prolonged or repeated inhalation may cause allergic respiratory reaction (asthma). Se~;tic>n 12: E«o.l9gicat.lnforn\ation Ecotoxicity: Not available. BODS and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic. Special Remarks on the Products of Biodegradation: Not available. •······· Sectio1'113:••pisposa1Consic:leratiol'ls•·•···· Waste Disposal: Dilute with water and flush to sewer of local ordinances allow, otherwise, whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Waste must be disposed of in accordance with federal, state and local environmental control regulations. •seC:tion 14: Transport lnformatiCin··· DOT Classification: Class 8: Corrosive material Identification: : Hypochlorite solution UNNA: 1791 PG: Ill Special Provisions for Transport: Not available. section 15: ottaer•RegiJiator)llnforrri.atiCII'I Federal and State Regulations: Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide New York release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide Pennsylvania RTK: Sodium hypochlorite; Sodium hydroxide Florida: Sodium hypochlorite Minnesota: Sodium hypochlorite; Sodium hydroxide Massachusetts RTK: Sodium hypochlorite; Sodium hydroxide New Jersey: Sodium hypochlorite; Sodium hydroxide Louisiana spill reporting: Sodium hydroxide TSCA B(b) inventory: Sodium hypochlorite; Sodium hydroxide; Water CERCLA: Hazardous substances.: Sodium hypochlorite: 100 lbs. (45.36 kg); Sodium hydroxide: 1000 lbs. (453.6 kg); Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications: p.6 WHMIS (Canada): CLASS E: Corrosive liquid. DSCL (EEC): RB-Contact with combustible material may cause fire. R31-Contact with acids liberates toxic gas. R36/38-Irritating to eyes and skin. S28-After contact with skin, wash immediately with plenty of water. S36/37139-Wear suitable protective clothing, gloves and eye/face protection. S45-In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.): Health Hazard: 3 Fire Hazard: 0 Reactivity: 0 Personal Protection: National Fire Protection Association (U.S.A.): Health: 1 Flammability: 0 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield. References: Not available. •_-Section .16: Other Information Other Special Considerations: Not available. Created: 10/0912005 06:32 PM Last Updated: 10/09/2005 06:32 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall SclenceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplar damages, howsoever arising, even p. 7 If Sc/enceLab.com has been advised of the possibility of such damages. p.8 Science ~ab .com Chemicals & Laboratory Equipment Material Safety Data Sheet Hydrochloric Acid, 33.3% MSDS Product Name: Hydrochloric Acid, 33.3% Catalog Codes: SLH 1138 CAS#: Mixture. RTECS: Not applicable. TSCA: TSCA 8(b) inventory: Water; Hydrochloric acid Cl#: Not applicable. Synonym: Hydrochloric Acid 33.3% (1 + 2) Solution Chemical Name: Not applicable. Chemical Formula: Not applicable. Composition: Name CAS# Water 7732-18-5 Hydrogen chloride 7647-01-0 Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: ScienceLab.com CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non-emergency assistance, call: 1-281-441-4400 %by Weight 86.7 12.3 Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat]. sectiOn 3; Hazards Identification ... Potential Acute Health Effects: Very hazardous in case of skin contact (irritant), of eye contact (irritant}, of ingestion, . Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive). Slightly hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Potential Chronic Health Effects: Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrogen chloride]. MUTAGENIC EFFECTS: Not available. p. 1 TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, , teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious Ingestion: Not available. ···· Sections; Fire~ridE.iq)losionoata · Flammability of the Product: Non-flammable. Auto-Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: of metals Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks. Fire Fighting Media and Instructions: Not applicable. Special Remarks on Fire Hazards: p.2 Non combustible. Calcium carbide reacts with hydrogen chloride gas with incandescence. Uranium phosphide reaCts with hydrochloric acid to release spontaneously flammable phosphine. Rubidium acetylene carbides burns with slightly warm hydrochloric acid. Lithium silicide in contact with hydrogen chloride becomes incandescent. When dilute hydrochloric acid is used, gas spontaneously flammable in air is evolved. Magnesium boride treated with concentrated hydrochloric acid produces spontaneously flammble gas. Cesium acetylene carbide burns hydrogen chloride gas. Cesium carbide ignites in contact with hydrochloric acid unless acid is dilute. Special Remarks on Explosion Hazards: Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violenVvigorous reaction: Acetic anhydride AgCIO + CCI4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCI vapor), 2-Amino ethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine+ dinitroanilines (evolves gas), Chlorosulfonic acid Cesium carbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylenediamine Ethylene imine, Fluorine, HCI04 Hexalithium disilicide H2S04 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate, beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCI), Sodium hydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbon tetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C. Small Spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. Large Spill: Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. ; iH<:·····•······· · ··secticillJ: HallQiill9'alld ~torll9e· :···.·· ·· Precautions: Keep locked up .. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, organic materials, metals, alkalis, moisture. Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. I H • . •·· .. > ·.· · ... ··.· .·· .. Section 8: Exposure Controls/Personal!lrotecti<>n • ···· ·······:•· .. ·. ···••···.·.· • < ··••··.··· .····••· Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection: Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots. Personal Protection in Case of a Large Spill: p. 3 Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Hydrogen chloride STEL: 7.5 (mg/m3) from ACGIH (TLV) [United States] STEL: 5 (ppm) from ACGIH (TLV) [United States] CEIL: 5 (ppm) from NIOSH CEIL: 7.5 (mg/m3) from NIOSH CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3) from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits. Physical state and appearance: Liquid. Odor: Not available. Taste: Not available. Molecular Weight: Not applicable. Color: Clear Colorless. pH (1% so In/water): Acidic. Boiling Point: The lowest known value is 100"C (212"F) (Water). Melting Point: Not available. Critical Temperature: Not available. Specific Gravity: Weighted average: 1.03 (Water = 1) Vapor Pressure: The highest known value is 2.3 kPa (@ 20"C) (Water). Vapor Density: The highest known value is 0.62 (Air= 1) (Water). Volatility: Not available. Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available. lonicity (in Water): Not available. Dispersion Properties: See solubility in water, diethyl ether. Solubility: Easily soluble in cold water, hot water. Soluble in diethyl ether. >i section 10: .stabilitY alld.·Reactivit'Y Oata••· . ........•.....•..• : .. ·••>•••·• ( .. · •.. Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Incompatible materials p.4 Incompatibility with various substances: Reactive with alkalis. Slightly reactive to reactive with oxidizing agents, organic materials, metals. Corrosivity: Extremely corrosive in presence of aluminum, of copper, of stainless steel(304), of stainless steel(316). Non-corrosive in presence of glass. Special Remarks on Reactivity: Absorption of gaseous hydrogen chloride on mercuric sulfate becomes violent @ 125 deg. C. Sodium reacts very violently with gaseous hydrogen chloride. Calcium phosphide and hydrochloric acid undergo very energetic reaction. It reacts with oxidizers releasing chlorine gas. Incompatible with, alkali metals, carbides, borides, metal oxides, vinyl acetate, acetylides, sulphides, phosphides, cyanides, carbonates. Reacts with most metals to produce flammable Hydrogen gas. Isolate hydrogen chloride from heat, direct, alkalies (reacts vigorously), organic materials(reacts vigorously with many organic materials), and oxidizers (especially nitric acid and chlorates), amines, metals, copper and alloys (e.g. brass), hydroxides, zinc (galvanized materials), lithium silicide (incandescence), sulfuric acid(increase in temperature and pressure) Hydrogen chloride gas is emitted when this product is in contact with sulfuric acid. Adsorption of Hydrochloric Acid onto silicon dioxide results in exothmeric reaction. Hydrogen chloride causes aldehydes and epoxides to violently polymerize. Hydrogen chloride or Hydrochloric Acid in contact with the folloiwng can cause explosion or ignition on contact or other violent/vigorous reaction: Acetic anhydride, Alcohols+ hydrogen cyanide, Aluminum, Aluminum phosphide, Aluminum-titanium alloys (with HCI vapor), 2-Amino ethanol, Ammonium, Ammonium hydroxide, 1 A-Benzoquinone diimine, Calcium acetylide (incandescence upon warming), Calcium carbide, Calcium phosphide, Carbon tetrachloride+ silver perchlorate (produce trichlormethyl perchlorate), Cesium acetylene carbide, Cesium carbide, Cesium telluroacylates, Chlorine+ dinitroanilines (evolves gas), Chloroacetaldehyde oxime, Chlorosulfonic acid, Cyanogen chloride (when catalyzed by HCI), 1, 1-Difiuoroethylene, Dinitroanilines, Ethylene, Ethylene diamine, Ethyl 2-formylpropionate oxime (when generated by using HCI as a catalyst), Ethylene imine, Fluorine, HCI04, Hexalithium disilicide, Hydrogen peroxide, Metal acetylides, carbides, Magnesium boride, Methyl vinyl ether, Mercuric sulfate, Nitric acid + glycerol, Oleum, Perchloric acid, Potassium, Potassium permanganate, beta-Propiolactone, Propylene oxide, Rubidium acetylide, Rubidium carbide, Rubidium acetyl en eca rbide, S il icon dioxide, S i lve rch lorite, Sod iu m(withaq u eou s H Cl), Sod iu m 2-allyloxy-6-nitrophenylpyruvate oxime, Sodium hydroxide, Sodium tetraselenium, Sulfonic acid, Sulfuric acid, T etraselenium tetranitride, 2,4,6-Tri(2-acetylhydrazino)-1 ,3,5-trinitrobenzene, Uranium phosphide, Vinyl acetate. Hydrogen chloride gas can react with formaldehyde to form bis(chloromethyl)ether, a human carcinogen. Most metals, as well as certain coatings, plastics, and rubbers, are attacked by hydrogen chloride. Addition of hydrochloric acid to the following results in an exothermic reaction: Cesium cyanotridecahydrodecarborate(2-), Potassium ferricyanide, Vinylidene fluoride. Addition of hydrochloric acid to potassium ferrocyanide or ammonium hexacyanoferrate(ll) results in an endothermic reaction. Hydrochloric acid in the presence of alcohol and glycols results in dehydration reactions. Special Remarks on Corrosivity: Highly corrosive. Incompatible with copper and copper alloys. It attacks nearly all metals (mercury, gold, platinium, tantalum, silver, and certain alloys are exceptions). It is one of the most corrosive of the nonoxidizing acids in contact with copper alloys. No corrosivity data on zinc, steel, or brass. Severe Corrosive effect on bronze Polymerization: Will not occur. Sectiorf t1 :.Toxicologicallnformatlorf Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. Toxicity to Animals: p.5 Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm/1 hours [Mouse]. Acute toxicity of the vapor (LC50): 3124 ppm/1 hours [Rat]. (Hydrochloric Acid) Chronic Effects on Humans: CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric Acid]. Contains material which may cause damage to the following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, , teeth. Other Toxic Effects on Humans: Extremely hazardous in case of eye contact (corrosive), of inhalation (lung corrosive). Very hazardous in case of skin contact (irritant), of ingestion, , Hazardous in case of skin contact (corrosive, permeator). Special Remarks on Toxicity to Animals: Lowest Published Lethal Doses (LDULCL) LDL [Man]-Route: Oral; 2857 ug/kg LCL [Human] -Route: Inhalation; Dose: 1300 ppm/30M LCL [Rabbit] -Route: Inhalation; Dose: 4413 ppm/30M (Hydrochloric Acid) Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects (fetoxicity). May affect genetic materiaL Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severe eye irritation/conjuntivitis, burns, corneal necrosis. Inhalation: May be fatal if inhaled. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract Inhalation of hydrochloric acid fumes produces noses, throat, and larryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking sensation, hoarseness, laryngeal spasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations. Inhalation of high concentrations can result in corrosive burns, necrosis of bronchial epithelium, constriction of the larynx and bronchi, dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can also occur, particularly if exposure is prolonged. May affect the liver. Ingestion: May be fatal if swallowed. Causes irritation and burning, ulceration, or perforation of the gastrointestinal tract and resultant peritonitis, gastric hemorrhage and infection. Can also cause nausea, vomitting (with "coffee ground" emesis), diarrhea, thirst, difficulty swallowing, salivation, chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affect behavior (excitement), the cardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinary system (kidneys-renal failure, nephritis). Acute exposure via inhalation or ingestion can also cause erosion of tooth enameL Chronic Potential Health Effects: Prolonged or repeated inhalation and/or ingestion may affect liver, bleeding of nose and gums, nasal and oral mucosal ulceration, conjunctivitis, respiratory tract (changes in pulmonary function, chronic bronchitis, overt respiratory tract abnormalities), teeth (yellowing of teethand erosion of tooth enamel), kidneys, and behavior (muscle contraction or spasticity). Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact with vapor/mist can cause conjunctivitis. (Hydrochloric Acid) Ecotoxicity: Not available. BODS and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may p.6 arise. Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself. Special Remarks on the Products of Biodegradation: Not available. ·····•·. section1~:pispo~ll:tcol'"lsiderati()lls·•···· Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. •.··.·.•····.·····.·. . . .,.,; DOT Classification: Class 8: Corrosive material Identification: : Hydrochloric Acid Solution UNNA: 1789 PG: II Special Provisions for Transport: Not available. ···.·····••••C:.sectiol'"lts:,ottlerRe!ll.llato!Y•II'"ItCII"maiioil••········· Federal and State Regulations: Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloric acid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTK hazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid Massachusetts RTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list: Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid TSCA 8{b) inventory: Water; Hydrochloric acid TSCA 4(a) proposed test rules: Hydrochloric acid SARA 302/304/311/312 extremely hazardous substances: Hydrochloric acid SARA 313 toxic chemical notification and release reporting: Hydrochloric acid 33.3% CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg); Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 191 0.1200). Other Classifications: WHMIS (Canada): CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid. DSCL (EEC): R25-Toxic if swallowed. R26-Very toxic by inhalation. R34-Causes burns. S1/2-Keep locked up and out ofthe reach of children. S26-In case of contact with eyes, rinse immediately with plenty of water and seek p. 7 medical advice. 828-After contact with skin, wash immediately with plenty of water. 836/37/39-Wear suitable protective clothing, gloves and eye/face protection. 845-In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.): Health Hazard: 3 Fire Hazard: 0 Reactivity: 0 Personal Protection: National Fire Protection Association (U.S.A.): Health: 2 Flammability: 0 Reactivity: 1 Specific hazard: Protective Equipment: Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield. References: Not available. Other Special Considerations: Not available. Created: 1 0/1 0/2005 1 0:34 AM Last Updated: 10/10/2005 10:34 AM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if 8cienceLab.com has been advised of the possibility of such damages. p.B Material Safety Data Sheet Sodium Hydroxide, 50% MSDS Product Name: Sodium Hydroxide, 50% Catalog Codes: SLS3127, SLS4549 CAS#: Mixture. RTECS: Not applicable. TSCA: TSCA 8(b) inventory: Sodium hydroxide; Water Cl#: Not applicable. Synonym: Sodium Hydroxide, 50% Solution Chemical Name: Not applicable. Chemical Formula: Not applicable. Composition: Name Sodium hydroxide Water CAS# 1310-73-2 7732-18-5 Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: Sciencelab.com CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non-emergency assistance, call: 1-281-441-4400 %by Weight 50 50 Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available. · ·• .··· Secti61l3i Hazards ldelltificatioll Potential Acute Health Effects: Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightly hazardous in case of inhalation (lung sensitizer). Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. p. 1 DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention immediately. Finish by rinsing thoroughly with running water to avoid a possible infection. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used .Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. lfbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Serious Ingestion: Not available. Flammability of the Product: Non-flammable. Auto-Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: Not applicable. Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks. Fire Fighting Media and Instructions: Not applicable. Special Remarks on Fire Hazards: Not available. p.2 Special Remarks on Explosion Hazards: Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of allyl benzenesulfonate prepared from allyl alcohol, and benzene sulfonyl chloride in presence of aquesous sodium hydroxide, ilnder vacuum distillation, residue darkened and exploded. Sodium Hydroxde + impure tetrahydrofuran, which can contain peroxides, can cause serious explosions. Dry mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at 230-270 deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol + trichlorobenzene + heat to cause an explosion. (Sodium hydroxide) Se!:tion 6;.At:cidentai .. Release Meas;IJres···•····· Small Spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of acetic acid. Large Spill: Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to r\)duce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. ·· ··· .. :section7:Handling arid Storage Precautions: Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture. · Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. .. c •. ....• · ....................... . •·· · • .·Section s:,Expos1.1re Corltroi~/Persona[Protectiori· Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Personal Protection: Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Sodium hydroxide STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/m3) from NIOSHConsult local authorities for acceptable exposure limits. Section 9: Phys;ical and Cllemical Properties; Physical state and appearance: Liquid. p.3 Odor: Odorless. Taste: Alkaline. Bitter. (Strong.) Molecular Weight: Not applicable. Color: Clear Colorless. pH (1 o/o soln/water): Basic. Boiling Point: 14o•c (284.F) Melting Point: 12•c (53.6.F) Critical Temperature: Not available. Specific Gravity: 1.53 (Water= 1) Vapor Pressure: The highest known value is 2.3 kPa (@ 2o•c) (Water). Vapor Density: The highest known value is 0.62 (Air= 1) (Water). Volatility: Not available. Odor Threshold: Not available. Water/Oil Dis!. Coeff.: Not available. lonicity (in Water): Not available. Dispersion Properties: See solubility in water. Solubility: Easily soluble in cold water. · sec:tion·1o:stabilitYal1d R!!activityoata'. Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Excess heat, incompatible materials, water/moisture Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, metals, acids, alkalis. Slightly reactive with water Corrosivity: Extremely corrosive in presence of aluminum, brass. Corrosive in presence of copper, of stainless stee1(304), of stainless steel(316). Non-corrosive in presence of glass. Special Remarks on Reactivity: Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold water and caution must be used for this process. Generates considerable heat when a sodium hydroxide solution is mixed with an acid Sodium hydroxide solution and octanol + diborane during a work-up of a reaction mixture of oxime and diborane in tetrahyrofuran is very exothermic, a mild explosion being noted on one occassion. Reactive with water, acids (mineral, non-oxidizing, e.g. hydrochloric, hydrofluoric acid, muriatic acid, phosphoric), acids (mineral, oxidizing e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), aldehydes (e.g. acetaldehyde, acrolein, chloral p.4 hydrate, foraldehyde), carbamates (e.g. carbanolate, carbofuran), esters (e.g. butyl acetate, ethyl acetate, propyl formate), halogenated organics (dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (acetone, acetophenone, MEK, MIBK), acid chlorides, strong bases, strong oxidizing agents, strong reducing agents, flammable liquids, powdered metals and metals (i.e aluminum, tin, zinc, hafnium, raney nickel), metals (alkali and alkaline e.g. cesium, potassium, sodium), metal compounds (toxic e.g. berylium, lead acetate, nickel carbonyl, tetraethyllead), mitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl cyanide), nitro compounds (organic e.g. nitrobenzene, nitromethane), acetic anhydride, hydroquinone, chlorohydrin, chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrosulfuric acid, oleum, propiolactone, acylonitrile, phorosous pentoxide, chloroethanol, chloroform-methanol, tetrahydroborate, cyanogen azide, 1 ,2,4,5 tetrachlorobenzene, cinnamaldehyde. Reacts with formaldehyde hydroxide to yield formic acid, and hydrogen. (Sodium hydroxide) Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of moisture. Polymerization: Will not occur. · ·•Secth>J111: T.oxic()Jogical Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Toxicity to Animals: LD50: Not available. LC50: Not available. Chronic Effects on Humans: Not available. Other Toxic Effects on Humans: Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (corrosive), of ingestion,. Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: Investigation as a mutagen (cytogenetic analysis), but no data available. (Sodium hydroxide) Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: May be harmful if absorbed through skin. Causes severe skin irritation and burns. May cause deep penetrating ulcers of the skin. Eyes: Causes severe eye irritation and burns. May cause chemical conjunctivitis and corneal damage. Inhalation: Harmful if inhaled. Causes severe irritation of the respiratory tract and mucous membranes with coughing, burns, breathing difficulty, and possible coma. Irritation may lead the chemical pneumonitis and pulmonary edema. Causes chemical burns to the respiratory tract and mucous membranes. Ingestion: May be fatal if swallowed. May cause severe and permanent damage to the digestive tract. Causes i ·.• · .... • .. ·.··. .. ·. · •.•. ······•··.····· .. · ·•••·••· Section12:.Ecologicallnformatiorl : ·• • · • .. · ................ ···· · Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself. Special Remarks on the Products of Biodegradation: Not available. p. 5 ·Section '13: Disposal ConsideratiC>n~· Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. · ·· sectiol\14: transpC>rtiriformation .. DOT Classification: Class 8: Corrosive material Identification:: Sodium hydroxide, solution (Sodium hydroxide} UNNA: UN1824 PG: II Special Provisions for Transport: Not available. ·•-······•·.· .. •· ···•·••···•····••-/ c ... ·•· <•· .. ·••·•• .. ··· section.15:()therRegulatol)f.lrlfonnation · Federal and State Regulations: Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide New York release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide Pennsylvania RTK: Sodium hydroxide Minnesota: Sodium hydroxide Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxide Louisiana spill reporting: Sodium hydroxide TSCA B(b) inventory: Sodium hydroxide; Water CERCLA: Hazardous substances.: Sodium hydroxide: 1000 lbs. (453.6 kg); ····>·····.················ .. :······ Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications: WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid. DSCL (EEC): HMIS (U.S.A.): Health Hazard: 3 Fire Hazard: 0 Reactivity: 1 Personal Protection: National Fire Protection Association (U.S.A.): Health: 3 Flammability: 0 Reactivity: 1 Specific hazard: Protective Equipment: p, 6 Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield. ···.··•··.·· .. ·······; ······.········ .. ..•.. ·.·•·~ection·1.6:0the(lnformation·.·.• · References: Not available. Other Special Considerations: Not available. Created: 10/09/2005 06:32 PM Last Updated: 10/09/2005 06:32PM ····· .. ·.· •• !·.········•··············. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the possibility of such damages. p. 7 »· February 2, 2009 Mark King Public Works Director Town Of Parachute POBox 100 Parachute, Colorado 81635 22? tJIJrth ?th S\rt-et ~26 !JJin S\1e2t Suil~ 2Db ~ Drl!a. W l\H\(1 RE: Garfield County Permit# 11180-Town of Parachute Filtration Building-Foundation and Pad Observation Dear Mark: Foundation-An observation was completed on January 131h, 2009. Site observation verified that all requirements were met including size and placement of the #4 and #5 rebar, minimum lap, and subgrade conditions. Pad -An observation ofthe building pad was completed on January 30'11, 2009. The observations verified all requirements were met including size and placement of the #4 rebar, subgrade conditions and gravel depth. Please call me if you have questions. Jessica Loveland, P. Project Manager cc: Garfield County Building and Planning Department Deb Jenson, Filter Tech Gary Blecha, Mor Storage File LETTER OF TRANSMITTAL: TO: Garfield County Building Dept. COMPANY: Garfield County 108 8'" st. Suite 401 Glenwood Springs, CO 81601 PHONE: FROM: lim Atkinson, PE DATE: 10/20/08 SUBJECT: Revell Springs Filtration Plant TRANSMITTAL METHOD: 0 Mail Items Included With This Transmittal: 0 Overnight ~ Courier 2 -copies of building plans, 1 -Bldg. permit application 0 Pickup Attached are the bldg. permit application, foundation plan, site plan, prefabricated building plans, and vicinity map for a new water filtration plant in Parachute Co. Please contact our office if you have any questions. Thank you, Office: (970) 874-6244 Fax: (970) 874-6118 JeHN Engineering 1 326 Main Street 1 Suite 206 I Delta, CO 81416 222 North 7th Street 1 Unit B I Grand Junction, CO 81501 Bill To: Garfield County Road and Bridge Department P.O. Box426 Rifle, CO 81650 Phone-(970)625-8601 Fax-(970)625-8627 Invoice Driveway Permit Number: GRBOS-D-117 Invoice Date: 11/5/2008 Town of Parachute 222 Grand Valley Way Parachute , CO 81635 $75.00 per Driveway Permit. DriveW_'!Y Permi!_~_::_: ______ _ Total Due: Thank You! $75.00 $75.00 RECEIVED NOV 0 5 2008 GARFIELD COU''JTY BUILDING & PLANNING » February 2, 2009 Mark King Public Works Director Town Of Parachute PO Box 100 Parachute, Colorado 81635 RE: Garfield County Permit# 11180-Town of Parachute Filtration Building-Foundation and Pad Observation Dear Mark: Foundation-An observation was completed on January 13'\ 2009. Site observation verified that all requirements were met including size and placement of the #4 and #5 rebar, minimum lap, and subgrade conditions. Pad-An observation of the building pad was completed on January 30'\ 2009. The observations verified all requirements were met including size and placement of the #4 rebar, subgrade conditions and gravel depth. Please call me if you have questions. Jessica Loveland, P. Project Manager cc: Garfield County Building and Planning Depmtment Deb Jenson, Filter Tech Gary Blecha, Mor Storage File From:TOWN OF PARACHUTE Feb 12 10 09:33a u1 v mon or rwgJstrauons Colorado Tbe oll~<:lal state Web Portal 970 285 0292 02/12/2010 10:42 r·."::·::·~ Dft•a ··l~;>~ VI~ Division of Registrations Departmlm1 of Rt•gula~ory Ag~nctt:os View Permit 663667 Requestor Site hl!IJI(IC!ions Electrical and Plumbing Permits Online Company Name: FRONTIER ELECTRIC First Name: DANIEL Last Name: HUTTON Address: 4S67VROAD cny: OESEQUE State: co Zipcooe: 81630 Phone: (970) 263-8821 Fax: ()· Email Aodress: frontler_elec@yahoo.eom License Number: 6087 Property Type: PRIVATE Property Owner: TOWN OF PARACHUTE Job Site Add ss: 120 CR 301 City: HUTE State: CO Zipcode: 81635 County: GARFIELD Power: HOLY CROSS· GLENWOOD SPRINGS Building Type: COMMERCIAL Construction Type: NEW Mise Construction: COMMERCIAL N!;W Cost Of Materials I Labor$: 7000 Trim: N ln&pected O~te Type Smtus 1QIQ212009 FINAl. ACCEPTED 09/Q112009 FINAL REJECTED 08118@0~ FINAL REJECTED #059 P.001/002 p.2 Page I of2 hrms://www.liom.smte.co.ns/nlslrco I/ en wch ncr mil "" i.show nav<l?n ""'r rvrx,=F.LI \(TR I C/\. ?.II ?/?.01 0 From:TOWN OF PARACHUTE Feb 12 10 09:3<\a vl v nHuu m 1\t:gu;m.uums !l.i'/9612009 I FINAl. Status/Actions Permit Number: Type: Stlltus: Opened: Expiration Date: Closed: Replaces: Replaced By: 970 285 0292 !ACCEPTED PARTIAL 663667 ELECTRICAL CLOSED 02/03/2009 02/03/2010 10/03/2009 NONE NONE I Email InSpector lJ OK 02/12/2010 10:43 Questions? Check out the !l.!llinil!9.o~ or f'reguenlly A'l!<ed questions (1'1\,Ql. Please take our~ to tell us abo~t your exper~noe with the online permits site. #059 P.002/002 p.3 Page 2 ol'2 Gsrmretf;l<Q; 0211212m0 09:.20 a.m. Usage Statistics Privacy Statement 1 Oisclalmru Federal Home Page II Stale Home Page 11 Oep@rtment H<>me Page TopofPaae Tec.hnlpat A.<!:f!in!l!!'l¢f1' f::.l'(l.~~.II)J~phnolggy_$f.<~ioo E-Mail the• ~~~~~~ 1s6o a Denver, (;!ll:l) !1\14 /1;'00 , PhCi10 (;$tl:\) KH4·'f6~~;; • Folx ll!:loY CQ!Q.t.Wll! (! 1"'\' \Lnuft•.;!i & SpnnirJt), VI),(!(!, VC(J. At:1CIL STN A!.r,,;,!:u·.(:(• Nwnt.lorB) h!lns://www.dom.stntc.cn,.,s/ols/real/en wch ncrmil' vui.show nauc?n "~'~ lvne""F.l ,1\(TRir.A... 2112/7.0 I 0 Parcel Detail Page 1 of2 Garfield County Assessor/Treasurer Parcel Detail Information Assessor/Txeasurer Pror:>e!1Y_s_e~arch I Assessor Subs.eLQuery I AssessQLSi!leJLS_e"ar.ch Cle;:k&Kecorder Reception Se"arch Earcel Detail I Va1ue.l2.etail I Slllesl2e1ail I ResidentiaUCommercial Imr:>rovementDe.tajJ Land Detail I PhQtQgmpm I Mill Leyy_JS__eyenues Detail I Tax Area II Account Number II Parcel Number II 2007 Mill Levy I I 047 II R470017 II 240707101002 II 38.002 I Owner Name and Mailing Address !GRAND VALLEY, TOWN OF !POBOX 100 !PARACHUTE, CO 81635-0100 Assessor's Parcel Description (Not to be used as a legal description) lsECT,TWN,RNG:7-7-95 SUB:HORBETZ lAD D. LOT:8 & DESC: WEST 2.0 AC. OF LOT9 Location I Physical Address: !!PARACHUTE Subdivision: IIHORBETZ ADD. Land Acres: I 5.1 Land Sq Ft: I 0 Section II Township II Range 7 II 7 II 95 2008 Property Tax Valuation Information I I I I I I I I I II Actual Value II Assessed Value IJ http://www. garcoact.com/ assessor/parcel.asp ?ParcelN umber=2407071 0 1 002 10/30/2008 Parcel Detail I Land: I 0 0 I Improvements: I 0 0 I Exempt: II 3o,oooll 8,7ool I Total: II 3o,oooll 8,7001 Additi011al Value Detail Most Recent Sale II Sale Date: I Sale Price: I Additional Sales Detail Basic Building Characteristics Nnmber of Residential 0 Buildings: Number of Comm/Ind 0 Buildings: No Building Records Found Tax Information No Tax Records Found Mill Leni~,evenues Detail T 012-ofJ'age 8$J>e,S,sor Database Sgar£hD,J2tion,;; I Irel!,Sl!rer Database~Sg_arch Qptions Clerk&_Ke_c_or,der Datahase_Se,an;h OmimJs Page 2 of2 The Garfield County Assessor and Treasurer's Offices make every effort to collect and maintain accurate data. However, Good Turns Software and the Garfield County Assessor and Treasurer's Offices are unable to warrant any of the information herein contained. Copyright © 2005 -2008 Good Turns Software. All Rights Reserved. Database & Web Design by Good Turns Softwm:e. http://www. garcoact.com! assessor/parcel.asp ?ParcelN umber=2407 071 01 002 ---·---- 10/30/2008