HomeMy WebLinkAboutEx 08b Water Supply and Quality letter 06.01.2020Wright Water Engineers, Inc.
818 Colorado Avenue, Suite 307, P.O. Box 219
Genwood Springs, Colorado 81602
(970) 945-7755 TEL
(970) 945-9210 FAX
June 1, 2020
Via Email
Richard Neiley, Esq.
Neiley Law Firm, LLC
6800 Highway 82, Suite 1
Glenwood Springs, CO 81601
w N.wrightwater.com
e-mail: jkelly viighiwater.com
Re: Water Supply Evaluation for Proposed Marble Fabrication and Warehouse Facility
Dear Mr. Neiley:
Wright Water Engineers, Inc. (WWE) has prepared this letter report to document the methodology
used to estimate the daily water demands for the proposed marble fabrication and warehouse
facility. In addition, we evaluated the adequacy of the physical water supply to meet the proposed
water demands. The facility is proposed to be developed on Parcel C of the Dixon Subdivision at
12744 Highway 82 in Garfield County, Colorado. In addition to the marble facility on Parcel C,
the project will include up to two residential units on each of Lot A and Parcel D. The well for the
facility is located on Lot A of the Dixon Subdivision and would serve Parcel C, Lot A, and Parcel
D.
WATER DEMAND
Based upon our correspondence, there are two proposed commercial structures totaling
approximately 30,000 square feet. The larger of the two buildings will be storage/warehouse and
a marble fabrication facility with a single restroom with a shower. The smaller building will have
two bathrooms without showers. Each building will have no more than 5 employees working
during an 8-hour shift. We understand that outdoor irrigation demand will be satisfied by the
irrigation ditch.
To estimate the daily water demand associated with these uses, WWE consulted the Garfield
County On -Site Wastewater Treatment System (OWTS) Regulations. Table 6-2 of the
Regulations provided estimates of average daily wastewater flow for various uses in gallons per
day (gpd). Table 6-2 provides estimates for "factories and plants exclusive of industrial
wastewater per employee per eight -hour shift" both with and without showers.
For the larger facility with shower(s), the wastewater production is estimated to be 35 gallons per
day (gpd) per employee per 8-hour shift. Therefore, the total wastewater flow is 175 gpd for up
to 5 employees. The smaller building is rated at 20 gpd per employee per 8-hour shift without
showers, or 100 gpd for up to 5 employees.
DENVER DURANGO
(303) 480-1700 TEL (303) 480-1020 FAX
(970) 259-7411 TEL (970) 259-8758 FAX
Richard Neiley, Esq.
June 1, 2020
Page 2
Therefore, the total estimated wastewater flow for the proposed facility is 275 gpd. Assuming that
90 percent of the water used at the facility becomes wastewater (10 percent consumption), the
water demand for the facility is approximately 306 gpd.
The proposed use of Lot A and Parcel D are residential with a maximum of 2 three -bedroom
dwellings per lot. Each residential unit is classified as a Single -Family Equivalent (SFE) by the
Garfield County Land Use and Development Code with water supply requirement of 350 gpd.
Therefore, the total water demand for Lot A and Parcel D is estimated to be up to 1,400 gpd.
WATER SUPPLIES
The property is served by the TePoel Well operating under Permit No. 45419-F-R (see attached)
located on Lot A of the Dixon Subdivision. The permit allows for pumping at a rate of up to 30
gallons per minute (gpm), and "the use of ground water from this well is limited to drinking and
sanitary purposes and the irrigation of 0.70 acres [sic] of landscaping/agricultural materials at the
Planted Earth." Historically, the well served a single-family residence and various uses and
facilities associated with the Planted Earth nursery and greenhouse. The property has shares in the
Lower Kelso Ditch Company, and the Kelso Ditch is the primary source of irrigation water for the
exiting nursery and greenhouse.
The existing well was drilled by Shelton Drilling on March 9, 2001 (see attached Well
Construction and Test Report). The well was drilled to a total depth of 141 feet encountering
Maroon Formation from depths of 74 feet to TD. The well was completed with perforated casing
in the bottom 40 feet of the well. The static water level at the time of drilling was 80 feet.
For the proposed facility, all potable uses will come from the TePoel Well and all landscape
irrigation will be provided by the Kelso Ditch.
WELL YIELD
A 20-gpm pump was installed by Samuelson Pump Company on April 19, 2001 (see attached
Pump Installation and Test Report). A pumping test was performed on April 20, with a static water
level of 82 feet, 4 inches. After pumping for an unknown time at 20 gpm, the water level was 83
feet, 21/2 inches.
WWE conducted a pumping test on the well on May 31, 2018. The well plumbing was configured
such that the well would cycle on to fill three pressure tanks and then cycle off while the tanks
emptied. Based on previous tests showing little drawdown, we determined that a 4-hour test would
likely be adequate.
Prior to starting the pumping test, the initial water level was 69.20 feet below the top of casing. The
pumping test was started at 10:15 am. The pumping test was performed by closing all valves to the
remainder of the property except for the pressure tanks. A hose was connected to a bib at the pressure
tank and turned on. A flow rate was also established by measuring the time it took to fill a 15-gallon
bucket from the hose. The discharge was approximately 10 to 12 gallons per minute.
Richard Neiley, Esq.
June 1, 2020
Page 3
For the first hour of the pumping test, a water level was acquired in the well, with the use of a
water level indicator. A measurement was taken about every minute and noted. During the
pumping test when the pump would cycle on, the water level would drop approximately 10 inches
and then maintain a constant depth. Once the pump would turn off, the water level would return
relatively quickly to where it was before the pump turned on. Figure 1 is a graph showing the
water level measurement during the pumping test.
The test was continued for another 3 hours until approximately 2:15 pm. During that time, the
water level was evaluated to verify there had not been any changes. During the last 15 minutes of
the pumping test, the water levels were evaluated once more and determined the same drawdown
and recover were taking place to a static water level of 69.40 feet below the top of casing. Since
recovery of the water level was almost immediate, there was no need to continue to monitor the
water level after the test had been completed. WWE estimated that between 2,400 and 2,880
gallons were pumped during the four-hour test.
The current property owner provided well meter readings from water year 2016 (See Table 1).
The records indicate the winter time use of about 1,070 gpd, then the water use ramping up to a
maximum of 6,345 gpd in June. It is unclear whether the additional use included irrigation, or just
additional uses associated with the nursery and greenhouse operation during the irrigation season.
Regardless, the data show that the well has demonstrated it is capable of supplying a water demand
in excess of 6,000 gpd.
WELL WATER QUALITY
WWE collected water quality samples for laboratory analysis near the end of the pumping test.
The suite of parameters tested are a subset of those parameters that have drinking water standards
that WWE typically uses for private well water supplies.
Table 2 summarizes the laboratory results for the well water. As shown in the table, none of the
parameters had a detected level that exceeded the primary or secondary standards, where
applicable. The water had a hardness of 344 mg/L, which is typical of well water completed in
bedrock. A water softener would be recommended to reduce scaling on pipes. The total dissolved
solids (TDS) was also high at 492 mg/L, making the water marginal for irrigation. Both of these
parameters are purely aesthetic and have no adverse health risk.
CONCLUSION
The water demand associated with the proposed marble fabrication and warehouse facility is
conservatively estimated to be 306 gpd. The residential water demand for Lot A and Parcel D is
estimated to be 1,400 gpd for 2 SFEs per lot. The total water demand for the proposed project is
1,706 gpd. The well has demonstrated both historically and during our pumping test to be able to
satisfy a demand of over 6,000 gpd, well in excess of the proposed demand. Therefore, the well
should be able to provide an adequate physical supply, especially because the outdoor irrigation
uses will be satisfied via the Kelso Ditch. The water quality of the well water showed good water
quality with the only treatment needed for aesthetic purposes and disinfection.
Richard Neiley, Esq.
June 1, 2020
Page 4
Please do not hesitate to call if you have any questions.
Very truly yours,
B
H WATER G ij RS, INC.
onathan M. Kel , P. .
enior Water Reso jes Engineer
Attachments: Well Permit No. 45419-F-R
Well Construction and Test Report
Pump Installation and Test Report
Figure 1 — Water Level Measurement
Table 1— 2016 Well Meter Readings
Table 2 — Water Quality Analysis
ACZ Laboratories Water Quality Report
G:\WWE\181-053\O10\Docs\Marble Facility Water Supply.docx
' Form No. OFFICE OF THE STATE ENGINEER
GWS-25 COLORADO DIVISION OF WATER RESOURCES
818 Centennial Bldg., 1313 Sherman St., Denver, Colorado 80203
(303) 866-3581
APPLICANT
1095
WELL PERMIT NUMBER 45419 -F R
DIV. 5 WD 38 DES. BASIN MD
Lot: A Block: Filing: Subdiv: DIXON
DIVIDE CREEK LAND & CATTLE CO
CIO LEAVENWORTH & KARP PC
P 0 DRAWER 2030
GLENWOOD SPRINGS, CO 81602-
(970) 945-2261
PERMIT TO CONSTRUCT A WELL
APPROVED WELL LOCATION
GARFIELD COUNTY
NW 1/4 SE 1/4 Section 27
Township 7 S Range 88 W Sixth P.M.
DISTANCES FROM SECTION LINES
2400 Ft. from South Section Line
1850 Ft. from East Section Line
UTM COORDINATES
Northing: Easting:
ISSUANCE OF THIS PERMIT DOES NOT CONFER A WATER RIGHT
CONDITIONS OF APPROVAL
1) This well shall be used in such a way as to cause no material injury to existing water rights. The issuance of this permit does not assure the
applicant that no injury will occur to another vested water right or preclude another owner of a vested water right from seeking relief in a civil
court action.
2) The construction of this well shall be in compliance with the Water Well Construction Rules 2 CCR 402-2, unless approval of a variance has
been granted by the State Board of Examiners of Water Well Construction and Pump Installation Contractors in accordance with Rule 18.
3) Approved pursuant to CRS 37-90-137(2) and State Engineer Hearing Case no. 92-SE-03 for the replacement of an existing well, permit no.
45419-F-R, appropriating ground water tributary to the Roaring Fork River, as an alternate point of diversion to the Basalt Conduit, on the
condition that the wet shall be operated only when the Basalt Water Conservancy District's substitute water supply plan, approved by the State
Engineer, is in effect and when a water allotment contract between the well owner and the Basalt Water Conservancy District for the release of
replacement water from Ruedi Reservoir is in effect, or under an approved plan for augmentation. BWCD contract #3.3.5.135(a). The old well
must be plugged and abandoned in accordance with Rule 16 of the Water Well Construction Rules. A Well Abandonment Report form must be
submitted within sixty (60) days after construction of the new well, affirming that the old well was plugged and abandoned.
4) The use of ground water from this well is limited to drinking and sanitary purposes and the irrigation of 0.70 acres of landscaping/agricultural
materials at the Planted Earth. All use of this well will be curtailed unless the water allotment contract or a plan for augmentation is in effect.
This well is known as TePoel Well, Water Court Case No. W-1506. Physical well address is 12744 Highway 82, Carbondale, CO 81623.
5) Approval of this replacement permit shall not result in an expanded use of ground water.
6) The maximum pumping rate of this well shall not exceed 30 GPM.
7) The average annual amount of ground water to be appropriated shall not exceed two (2) acre-foot (651,700 gallons).
8) The owner shall mark the well in a conspicuous place with well permit number(s), name of the aquifer, and court case number(s) as
appropriate. The owner shall take necessary means and precautions to preserve these markings.
9) A totalizing flow meter must be installed on this well and maintained in good working order. Permanent records of all diversions must be
maintained by the well owner (recorded at least annually) and submitted to the Division Engineer upon request.
10) This well shall be constructed not more than 200 feet from the location specified on this permit.
11) This well shall be constructed at least 600 feet from any existing well, except permit nos. 164088 and 162494, which were the subject of
State Engineer Hearing Case no. 92-SE-03 or any well that is not owned by the applicant.
12) The change/expansion of use from the decreed use of this well (TePoel Well, Case no. W-1506) is a change in water right. An application
should be made to the Division 5 Water Court for this change of water right.
NOTE: Parcel Identification Number (PIN): 23-2393-274-01-003
NOTE: Assessor Tax Schedule Number: R112089
APPROVED
DMW
Receipt No. 9500488
440
State Engineer
DATE 1SSUEDMAR 0 7 2001
o 3,77a�/
B EXPIRATION DATMAR 0 7 2002
/ WELL CONSTRUCTION AND TEST REPORT
STATE OF COLORADO, OFFICE OF THE STATE ENGINEER
FOR OFFICE USE ONLY
RECEIt1Fn
.... MAR 21 2001
WAT€,4rk.,, 4
STATE EtiG;NEER
APPROVAL # aWS31-91-03
1.
WELL PERMIT NUMBER 045419-F-R
2.
Owner Name(s) : Divide Creek Land & Cattle
Mailing Address : 12744 Hwy 82
City, St. Zip : Carbondale, Co. 81623
Phone (970) 963-1731
3.
WELL LOCATION AS DRILLED: NW 114 SE 1/4 Sec. 27 Twp. 073 Range 88W
DISTANCES FROM SEC. LINES:
2400 ft. from South Sec. line. and 1850 ft. from East Sec. line. OR
SUBDIVISION : Dixon LOT A BLOCK FILING(UNIT)
STREET ADDRESS AT WELL LOCATION :
4
GROUND SURFACE ELEVATION ft. DRILLING METHOD Air Rotary
DATE COMPLETED 03/09/01 TOTAL DEPTH 141 ft. DEPTH COMPLETED 141 ft.
5. GEOLOGIC LOG :
6. HOLE DIAM. (in)
FROM (ft)
TO (ft)
Depth
Type of Material (Size, Color, and Type)
9.0
0
74
000-035
Red Dirt, Rocks
6.5
74
141
035-074
Maroon formation (Broken, Loose)
074-141
Maroon formation
7. PLAIN CASING
OD (in)
Kind
Wall Size
From (ft)
To (ft)
7.0
1 Steel
0.240
-1
74
5.5
PVC
.250
41
101
PERF. CASING : Screen Slot Size :
5.5
PVC
.250
101
141
WATER LOCATED : 100+
REMARKS :
8. Filter
Material
Size :
Interval
Pack
:
:
9. Packer Placement
Type :
Depth :
10. GROUTING RECORD :
Material
Amount
Density
Interval
Placement
cement
5 sks
16 gal
10-40
poured
L
11. DISINFECTION : Type : HTH Amt. Used : oz.
12. WELL TEST DATA :11 Check Box If Test Data is Submitted On Supplemental Form.
TESTING METHOD : Air Compressor
Static Level : 80 ft. Date/Time Measured : 3/9f01 Production Rate : 30 gpm
Pumping Level : Total ft. Date/Time Measured : 3/9/01 Test Length : 2 hrs.
Remarks :
13. l have read the slatemer,ts made herein end know the contents thereof, and that they are true to my knowledge. (Pursuant to Section 24-4-104 (13)(a) CRS, the making or false statements constitutes perjury
second nee and is punishable as a class Ile.)
ail
CONTRACTOR : Shelton Drilling Corp. Phone : (970) 927-4182
Mailing Address : P.O. Box 1059 Basalt, GO.: : Lic. No. 1095
Name / Title (Please Type or Print)
Wayne Shelton / President
Sign 'et
Date 03/19/01
,. -
�J
ORIGINAL
FORM NO.
GWS-32
10/94
/ . PUMP INSTALLATION AND
TEST REPORT
THE STATE ENGINEER
For Office , Lite only
HECEIVED
95d o 4 ?
MAY 2 3 2001
valtR REisouKcis
simE
STATE OF COLORADO, OFFICE OF
1.
WELL PERMIT NUMBER 4541 a — F ae
2.
OWNER
Mailing
City,
Phone
p I " g G Rk • I A uu 14 Crt fT1.t3 CV,
NAME(S) 7° La V +,/ oicr-rt-i /(OP P p-C_
Address P..0. f11 .AWt 2.s5310
St. Zip G(.1k)vJeg7N 5p r,.) a3• tir16C2
(120) '145- zair i
3.
WELL LOCATION AS DRILLED: 'VW 1/4 SE 1/4, Sec. 22 Twp. r7 5 , Range ' &
,
DISTANCES FROM SEC. LINES:
2400 ft. from 50 Lick Sec. line. and I o ft. from �`r4- T Sec. line.
FILING(UNIT)
SUBDIVISION:
STREET
(norm or swim tease or west)
LOT BLOCK
_
ADDRESS AT WELL LOCATION:
4.
PUMP DATA: Type SvrSMele-sr 8 Installation Completed 4//1/0l
Pump
Design
Pump
ADDITIONAL
Manufacturer STW —GC IT8 Pump M:,.-ial No. 2ow4Foz14--O
GPM z J at RPM -34,$0 , HP / P Or , Volts zs o v , Full Load Amps //- Z
Intake Depth 1 z ' Feet, Drop/Column Pipe Size / r4 Inches, Kind l'cy joPVC.,
INFORMATION FOR PUMPS GREATER THAT 50 GPM:
TURBINE
Design
DRIVER TYPE: ❑ Electric ■ Engine ❑ Other
Head feet, Number of Stages , Shaft size inches.
5.
OTHER EQUIPMENT:
. Monitor Tube Installed
Depth ft.
Airline
Flow
Meter
Installed U Yes ® No, Orifice Depth ft.
EJ Yesa No,
Meter Mfg. Meter Serial No. _
Readout ❑ Gallons, ❑ Thousand Gallons,. Acre feet, 0 Beginning Reading
6.
TEST
is submitted on Supplemental Form.
l azi/v r'
DATA: ❑ Check box if Test data
Total
Static
Date
Date
Well Depth 1 "30 Time
Level Scz'- 4 " Rate (GPM) 20 Gta&a-
Measured 4/oJrlr Pumping Lvl. 1M1-722_ C'
7.
DISINFECTION:
Type c u.)14.17J, Amt. Used 1GfaZ-
8.
Water Quality analysis available. ❑ Yes JZ No
9.
Remarks
10.
CONTRACTOR
Mailing
I have
[Pursuant
degree
read the statements made herein and know the contents thereof, and that they are true to my knowledge.
to Section 24-4-104 (13)(a) C.R.S., the making of false statements herein consf Lutes perjury in the second
and is punishable as a class 1 misdemeanor.]
S muri— OIV I�VMP ' . 1 t • Phone (970) 945-6309 Lic. No. I OSO .
Address .0. tin :.97 rILE1UL0001, 7SPr: iLI r2:'j,r4,1 . Zf s'OZ
Name/Title (Please type or print)
PAL/S4 M u FL50N PP -ES -
PAL/kJ
Signature
el..,
Date
5 2./ 6/
- 68.8
- 69
-69.2
- 69.8
- 70
-70.2
FIGURE 1
TePoel Well
Water Level Measurement May 31, 2018
I
- 70.4
4 4 "4 4"4 4 4""""4 4 4 4 4*""*""""444 4 4 44OP
4
PPPPPPPPPPPPPPPPPPPPPP% � .1O '° 1 b oi O L Oh `bN•N•yP,P, 33t1)4 R)4 A5,5, 5, h5.,o• • o• o• o• o• o• o• o• o• o•o• • • o• •o• • o•o• o• o• • o•o• o• ti• • titititititititititititititi tiv titi
Time
G:\WWE\181-053\000\Engr\Pumping Test\
Water Level Data.xlsx
Wright Water Engineers, Inc. Prepared By: MO
July 10, 2018 Checked By: SDS
TePoel Well
Well Water Level Measurement - May 31, 2018
Time
Water Level
(ft)
Note
10:15:00 AM
69.21
Pump off
10:17:04 AM
69.21
Pump on
10:17:38 AM
69.8
10:19:10 AM
70.1
Pump off
10:19:40 AM
69.35
10:20:40 AM
69.31
10:21:30 AM
69.28
10:23:07 AM
69.27
Pump on
10:23:34 AM
69.92
10:23:46 AM
70
10:24:08 AM
70.05
10:25:07 AM
70.08
Pump off
10:25:49 AM
69.41
10:27:12 AM
69.3
10:28:59 AM
69.28
Pump on
10:29:13 AM
69.8
10:29:47 AM
70
10:30:00 AM
70.1
10:31:01 AM
70.17
Pump off
10:32:50 AM
69.7
10:33:07 AM
69.3
10:34:22 AM
69.28
10:34:56 AM
69.2
Pump on
10:35:52 AM
70.03
10:36:21 AM
70.08
10:37:04 AM
70.15
Pump off
10:37:39 AM
69.4
10:39:21 AM
69.33
10:40:22 AM
69.3
10:41:04 AM
69.28
Pump on
10:41:31 AM
70
10:42:17 AM
70.1
10:43:03 AM
70.12
Pump off
10:43:49 AM
69.4
Time
Water Level
(ft)
Note
10:46:33 AM
69.31
10:46:52 AM
69.3
Pump on
10:47:24 AM
70
10:47:40 AM
70.05
10:48:25 AM
70.1
10:49:10 AM
70.11
Pump off
10:49:37 AM
69.5
10:49:52 AM
69.4
10:51:19 AM
69.32
10:52:52 AM
69.3
Pump on
10:53:23 AM
70
10:53:55 AM
70.1
10:54:56 AM
70.11
Pump off
10:55:32 AM
69.45
10:55:58 AM
69.4
10:57:03 AM
69.35
10:58:01 AM
69.31
Pump on
10:58:50 AM
69.31
10:59:17 AM
69.91
10:59:25 AM
70
10:59:32 AM
70.05
10:59:50 AM
70.1
11:00:55 AM
70.13
Pump off
11:01:50 AM
69.4
11:02:59 AM
69.35
11:04:11 AM
69.32
11:04:47 AM
69.32
Pump on
11:05:06 AM
69.9
11:05:26 AM
70
11:05:44 AM
70.1
11:06:49 AM
70.13
Pump off
11:07:18 AM
69.5
11:08:01 AM
69.4
G:\WWE\181-053\000\Engr\Pumping Test\
Water Level Data.xlsx
TABLE 1
HIPA HIPA LLC
WATER RIGHTS DIVERSIONS
Year: 2016
MONTH
DAY
METER
READING
DIVERSION AMOUNT
GALLONS
GALLONS PER DAY
ACRE FEET
NOVEMBER '15
1
2,480,390
DECEMBER'15
3
2,510,400
30,010
1,072
0.09
JANUARY
-
0
0.00
FEBRUARY
-
0
0.00
MARCH
-
0
0.00
APRIL
5
2,630,201
119,801
4,792
0.37
MAY
2,720,406
90,205
2,910
0.28
JUNE
2,910,765
190,359
6,345
0.58
JULY
3,000,295
89,530
2,888
0.27
AUGUST
3,050,775
50,480
1,628
0.15
SEPTEMBER
3,104,325
53,550
1,785
0.16
OCTOBER
31
3,207,300
102,975
3,322
0.32
G:\WWE\181-053\000\Engr\Diversion Records\
2016 Diversions.xlsx
TABLE 2
Water Quality Analysis Sampled on May 31, 2018
M ANALYTE
MIN
Method'
Tepoel Well ,
MCL' MCLG2 SMCL3
Aluminum (Total)
mg/L
EPA 200.7
<0.03
0.050-0.2
Antimony (Total)
mg/L
EPA 200.8
<0.0004
0.006
0.006
Arsenic (Total)
mg/L
EPA 200.8
0.001
0.010
0
Barium (Total)
mg/L
EPA 200.7
0.020
2
2
Beryllium (Total)
mg/L
EPA 200.8
<0.00005
0.004
0.004
Cadmium (Total)
mg/L
EPA 200.7
<0.005
0.005
0.005
Calcium (Dissolved)
mg/L
EPA 200.7
84.3
Chromium (Dissolved)
mg/L
EPA 200.7
<0.01
0.1
0.1
Copper (Total)
mg/L
EPA 200.7
<0.01
1.3
1.3
1.0
Iron (Total)
mg/L
EPA 200.7
<0.02
0.3
Lead (Total)
mg/L
EPA 200.8
0.0005
0.015
0
Magnesium (Dissolved)
mg/L
EPA 200.7
32.5
Manganese (Total)
mg/L
EPA 200.7
<0.005
0.05
Mercury (Total)
mg/L
EPA 245.1
<0.0002
0.002
0.002
Nickel (Total)
mg/L
EPA 200.7
<0.008
0.1
Potassium (Dissolved)
mg/L
EPA 200.7
2.4
Selenium (Total)
mg/L
EPA 200.8
0.002
0.05
0.05
Silica (Dissolved)
mg/L
EPA 200.7
27.1
Silver (Total)
mg/L
EPA 200.7
<0.01
0.10
Sodium (Dissolved)
mg/L
EPA 200.7
38.0
Thallium (Total)
mg/L
EPA 200.8
<0.0001
0.002
0.0005
Uranium
mg/L
EPA 200.8
0.0091
Zinc (Total)
mg/L
EPA 200.7
<0.01
5
Alkalinity, Total as CaCO3
mg/L
SM2320B
267
Chloride
mg/L
SM4500CI-E
10.8
250
Corrosivity, Langelier Index
SM 2330
1.1
Cyanide, Total
mg/L
EPA 335.4
<0.003
0.2
0.2
Fluoride
mg/L
SM4500E-C
0.44
4
4
2
Hardness, Total as CaCO3
mg/L
SM 2340B
344
Nitrogen, Nitrate
mg/L
NO3NO2-NO2
0.89
10
10
Nitrogen, Nitrate+Nitrite
mg/L
EPA 353.2
0.89
Nitrogen, Nitrite
mg/L
EPA 353.2
<0.01
1
1
pH
su
SM4500H+B
8.2
6.5-8.5
Phosphorus, Total
mg/L
EPA 365.1
<0.02
Solids, Total Dissolved
mg/L
SM2540C
492
Solids, Total Suspended
mg/L
SM2540D
<5
Specific Conductivity
umhos/cm
SM2510B
754
Sulfate
mg/L
SM4500 SO4-D
130
250
Turbidity
NTU
EPA 180.1
<0.1
0.5
Gross Alpha
pCi/L
7.3
15
Gross Beta
pCi/L
3.3
50
'Maximum Contaminant Level (MCL) - The highest level of a contaminant that is allowed in drinking water.
MCLs are set as close to MCLGs as feasible using the best available treatment technology and taking
cost into consideration. MCLs are enforceable standards.
2Maximum Contaminant Level Goal (MCLG) - The level of a contaminant in drinking water below which there is
no known or expected risk to health. MCLGs allow for a margin of safety and are non -enforceable
public health goals.
3National Secondary Drinking Water Regulations (NSDWRs or secondary standards) are non -enforceable
guidelines regulating contaminants that may cause cosmetic effects (such as skin or tooth discoloration)
or aesthetic effects (such as taste, odor, or color) in drinking water. EPA recommends secondary
standards to water systems but does not require systems to comply.
G:\WWE\181-053\000\Engr\Water Quality\ Wright Water Engineers, Inc.
Table 2 WQ Results.xlsx July 10, 2018
Prepared By: MO
Checked By: JMK
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Project ID: 181-053.000
Sample ID: WELL TEPEOL
Inorganic Analytical
Results
ACZ Sample ID:
Date Sampled:
Date Received:
Sample Matrix:
L44642-01
05/31/18 14:56
06/01/18
Drinking Water
Inorganic Prep
Parameter
Cyanide, total
Phosphorus, total
Total Recoverable
Digestion
Total Recoverable
Digestion
Metals Analysis
EPA Method
M335.4 - Manual Distillation
M365.1 - Auto Ascorbic
Acid Digestion
M200.2 ICP-MS
M200.2 ICP
Dilution Result Qual XQ Units M
PQL
Date Analyst
06/14/18 10:08 jig
06/06/18 14:13 jlg/las
06/06/18 13:08 mfm
06/19/18 10:19 dcm
Parameter
EPA Method
Dilution Result Qual XQ Units MDL PQL
Date Analyst
Aluminum, total
recoverable
Antimony, total
recoverable
Arsenic, total
recoverable
Barium, total
recoverable
Beryllium, total
recoverable
Cadmium, total
recoverable
Calcium, dissolved
Chromium, dissolved
Copper, total
recoverable
Iron, total recoverable
Lead, total recoverable
Magnesium, dissolved
Manganese, total
recoverable
Mercury, total
Nickel, total
recoverable
Potassium, dissolved
Selenium, total
recoverable
Silica, dissolved
Silver, total recoverable
Sodium, dissolved
Thallium, total
recoverable
Uranium, total
recoverable
Zinc, total recoverable
M200.7 ICP
M200.8 ICP-MS
M200.8 ICP-MS
M200.7 ICP
M200.8 ICP-MS
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.8 ICP-MS
M200.7 ICP
M200.7 ICP
M245.1 CVAA
M200.7 ICP
M200.7 ICP
M200.8 ICP-MS
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.8 ICP-MS
M200.8 ICP-MS
M200.7 ICP
1
1
1 0.001 B
1 0.020
1 U
1 U
84.3
1
1 0.0005
1 32.5
1
mg/L
0.03
0.2
06/20/18 17:30
aeh
mg/L 0.0004 0.002 06/14/18 13:08 bsu
mg/L 0.0005 0.002 06/14/18 13:08 bsu
mg/L 0.003 0.02
06/20/18 17:30 aeh
mg/L 0.00005 0.0003 06/14/18 13:08 bsu
mg/L 0.005 0.02
mg/L
U mg/L
U mg/L
1 2.4
1 0.002 B
1 27.1
1 U
1 38.0
1 U
1 0.0091
1
mg/L
mg/L
mg/L
mg/L
0.1
0.01
0.01
0.5
0.05
0.05
0.02 0.05
0.0001 0.0005
0.2 1
0.005 0.03
06/20/18 17:30 aeh
06/19/18 4:50
06/19/18 4:50
06/20/18 17:30
06/20/18 17:30
06/14/18 13:08
06/19/18 4:50
06/20/18 17:30
dcm
dcm
aeh
aeh
bsu
dcm
aeh
mg/L 0.0002 0.001 06/16/18 11:34 the
mg/L 0.008 0.04 06/20/18 17:30 aeh
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0.2 1 06/19/18 4:50 dcm
0.001 0.005 06/14/18 13:08 bsu
0.2 1
0.01 0.03
0.2 1
0.0001 0.0005
06/19/18 4:50
06/20/18 17:30
06/19/18 4:50
06/14/18 13:08
dcm
aeh
dcm
bsu
mg/L 0.0001 0.0005 06/14/18 13:08 bsu
mg/L 0.01 0.05
06/20/18 17:30 aeh
REPIN.02.06.05.01
" Please refer to Qualifier Reports for details.
L44642-1806221021 Page 2 of 22
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Project ID: 181-053.000
Sample ID: WELL TEPEOL
Inorganic Analytical
Results
ACZ Sample ID:
Date Sampled:
Date Received:
Sample Matrix:
L44642-01
05/31/18 14:56
06/01/18
Drinking Water
Wet Chemistry
Parameter
EPA Method
Dilution Result Qual XQ Units MDL PQL
Alkalinity as CaCO3
Bicarbonate as
CaCO3
Carbonate as CaCO3
Hydroxide as CaCO3
Total Alkalinity
Cation -Anion Balance
Cation -Anion Balance
Sum of Anions
Sum of Cations
Chloride
Conductivity @25C
Corrosivity (calc.)
Cyanide, total
Fluoride
Hardness as CaCO3
(dissolved)
Lab Filtration (0.45um
filter)
Lab Filtration (0.45um)
& Acidification
Nitrate as N, dissolved
Nitrate/Nitrite as N,
dissolved
Nitrite as N, dissolved
pH (lab)
pH
pH measured at
Phosphorus, total
Residue, Filterable
(TDS) @180C
Residue, Non -
Filterable (TSS)
@105C
Sulfate
TDS (calculated)
TDS (ratio -
measured/calculated)
Turbidity
SM2320B - Titration
Calculation
SM4500CI-E
SM2510B
SM 2330 - CaCO3 SI
M335.4 - Colorimetric w/ distillation
SM4500E-C
SM2340B - Calculation
SO P W C050
M200.7/200.8
Calculation: NO3NO2 minus NO2
M353.2 - Automated
Cadmium Reduction
M353.2 - Automated
Cadmium Reduction
SM4500H+ B
M365.1 - Auto Ascorbic
Acid (digest)
SM2540C
SM2540D
SM4500 SO4-D
Calculation
Calculation
Date Analyst
267 mg/L 2 20 06/12/18 0:00 ecc
267
mg/L
mg/L
mg/L
2 20 06/12/18 0:00 ecc
2 20 06/12/18 0:00 ecc
2 20 06/12/18 0:00 ecc
0.6 %
8.5 meq/L
8.6 meq/L
1 10.8 * mg/L 0.5 2
1 754 umhos/cm 1 10
1.1 * SI Unit
0.5 U * mg/L 0.003 0.01
1 0.44 mg/L 0.05 0.3
344 mg/L 0.2 5
M180.1 - Nephelometric 1
0.89
0.89
8.2
20.2
492
130
500
0.98
U
H
U
U
mg/L 0.02 0.1
mg/L 0.02 0.1
mg/L 0.01 0.05
units 0.1 0.1
C 0.1 0.1
mg/L 0.02 0.05
mg/L 10 20
mg/L 5 20
mg/L 10 50
mg/L
NTU 0.1 0.5
06/22/18 0:00 calc
06/22/18 0:00 calc
06/22/18 0:00 calc
06/18/18 13:20 wtc
06/12/18 17:21 ecc
06/22/18 0:00 calc
06/14/18 23:42 pjb
06/18/18 18:09 enb
06/22/18 0:00 calc
06/18/1811:25 enb
06/15/18 15:30 aeh
06/22/18 0:00 calc
06/01/18 21:48 pjb
06/01/18 21:48 pjb
06/12/18 0:00 ecc
06/12/18 0:00 ecc
06/12/18 15:40 wtc
06/06/18 13:48 kja
06/06/18 17:28 oah
06/18/1811:57 enb
06/22/18 0:00 calc
06/22/18 0:00 calc
06/01/18 16:32 emk
REPIN.02.06.05.01
* Please refer to Qualifier Reports for details.
L44642-1806221021 Page 3 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Inorganic
Reference
Report Header Explanations
Batch
Found
Limit
Lower
MDL
PCN/SCN
PQL
QC
Rec
RPD
Upper
Sample
A distinct set of samples analyzed at a specific time
Value of the QC Type of interest
Upper limit for RPD, in %.
Lower Recovery Limit, in % (except for LCSS, mg/Kg)
Method Detection Limit. Same as Minimum Reporting Limit unless omitted or equal to the PQL (see comment #5).
Allows for instrument and annual fluctuations.
A number assigned to reagents/standards to trace to the manufacturer's certificate of analysis
Practical Quantitation Limit. Synonymous with the EPA term "minimum level".
True Value of the Control Sample or the amount added to the Spike
Recovered amount of the true value or spike added, in % (except for LCSS, mg/Kg)
Relative Percent Difference, calculation used for Duplicate QC Types
Upper Recovery Limit, in % (except for LCSS, mg/Kg)
Value of the Sample of interest
QC Sample Types
AS
ASD
CCB
CCV
DUP
ICB
lCV
ICSAB
LCSS
LCSSD
LCSW
Analytical Spike (Post Digestion)
Analytical Spike (Post Digestion) Duplicate
Continuing Calibration Blank
Continuing Calibration Verification standard
Sample Duplicate
Initial Calibration Blank
Initial Calibration Verification standard
Inter -element Correction Standard - A plus B solutions
Laboratory Control Sample - Soil
Laboratory Control Sample - Soil Duplicate
Laboratory Control Sample - Water
LCSWD
LFB
LFM
LFMD
LRB
MS
MSD
PBS
PBW
PQV
SDL
Laboratory Control Sample - Water Duplicate
Laboratory Fortified Blank
Laboratory Fortified Matrix
Laboratory Fortified Matrix Duplicate
Laboratory Reagent Blank
Matrix Spike
Matrix Spike Duplicate
Prep Blank - Soil
Prep Blank - Water
Practical Quantitation Verification standard
Serial Dilution
QC Sample Type Explanations
Blanks
Control Samples
Duplicates
Spikes/Fortified Matrix
Standard
Verifies that there is no or minimal contamination in the prep method or calibration procedure.
Verifies the accuracy of the method, including the prep procedure.
Verifies the precision of the instrument and/or method.
Determines sample matrix interferences, if any.
Verifies the validity of the calibration.
ACZ Qualifiers (Qual)
B Analyte concentration detected at a value between MDL and PQL. The associated value is an estimated quantity.
H Analysis exceeded method hold time. pH is a field test with an immediate hold time.
L Target analyte response was below the laboratory defined negative threshold.
U The material was analyzed for, but was not detected above the level of the associated value.
The associated value is either the sample quantitation limit or the sample detection limit.
Method References
(1)
(2)
(3)
(4)
(5)
Comments
(1)
(2)
(3)
(4)
(5)
EPA 600/4-83-020. Methods for Chemical Analysis of Water and Wastes, March 1983.
EPA 600/R-93-100. Methods for the Determination of Inorganic Substances in Environmental Samples, August 1993.
EPA 600/R-94-111. Methods for the Determination of Metals in Environmental Samples - Supplement I, May 1994.
EPA SW-846. Test Methods for Evaluating Solid Waste.
Standard Methods for the Examination of Water and Wastewater.
QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations.
Soil, Sludge, and Plant matrices for Inorganic analyses are reported on a dry weight basis.
Animal matrices for Inorganic analyses are reported on an "as received" basis.
An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification qualifier
associated with the result.
If the MDL equals the PQL or the MDL column is omitted, the PQL is the reporting limit.
For a complete list of ACZ's Extended Qualifiers, please click: http://www.acz.com/public/extquallist.pdf
REP001.03.15.02
L44642-1806221021
Page 4 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Alkalinity as CaCO3
SM2320B - Titration
ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449279
WG449279PBW1 PBW 06/12/18 15:56 U mg/L
WG449279LCSW3 LCSW 06/12/18 16:13 WC180531-2 820.0001 815 mg/L 99 90 110
L44675-01DUP DUP 06/12/18 18:08 129 130 mg/L
WG449279LCSW6 LCSW 06/12/18 19:48 WC180531-2 820.0001 823 mg/L 100 90 110
WG449279PBW2 PBW 06/12/18 19:55 U mg/L -20 20
WG449279LCSW9 LCSW 06/12/18 23:07 WC180531-2 820.0001 808 mg/L 99 90 110
WG449279PBW3 PBW 06/12/18 23:14 2 mg/L -20 20
WG449279LCSW12 LCSW 06/13/182:03 WC180531-2 820.0001 827 mg/L 101 90 110
WG449279PBW4 PBW 06/13/18 2:10 U mg/L -20 20
WG449279LCSW15 LCSW 06/13/18 5:40 WC180531-2 820.0001 834 mg/L 102 90 110
-20
20
1 20
Aluminum, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 1.93 mg/L 97 95 105
WG4499811CB ICB 06/20/18 17:08 U mg/L -0.09 0.09
WG449789LRB LRB 06/20/18 17:24 U mg/L -0.066 0.066
WG449789LFB LFB 06/20/18 17:27 11180608-2 1.0019 1.008 mg/L 101 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 1.0019 .16 1.2 mg/L 104 70 130
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 1.0019 .16 1.195 mg/L 103 70 130 0 20
Antimony, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec%
D Limit Qual
WG449470
WG4494701CV ICV 06/14/18 12:59 MS180423-2 .02 .01853 mg/L 93 90 110
WG4494701CB ICB 06/14/18 13:01 U mg/L-0.0012 0.0012
WG448814LRB LRB 06/14/18 13:04 U mg/L-0.00088 0.00088
WG448814LFB LFB 06/14/18 13:05 MS180522-2 .01 .01059 mg/L 106 85 115
L44655-01LFM LFM 06/14/18 13:12 MS180522-2 .01 U .01082 mg/L 108 70 130
L44655-01LFMD LFMD 06/14/18 13:13 MS180522-2 .01 U .01107 mg/L 111 70 130 2 20
Arsenic, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06/14/18 12:59 MS180423-2 .05 .04996 mg/L 100 90 110
WG4494701CB ICB 06/14/18 13:01 U mg/L -0.0015 0.0015
WG448814LRB LRB 06/14/18 13:04 U mg/L-0.0011 0.0011
WG448814LFB LFB 06/14/18 13:05 MS180522-2 .0501 .04901 mg/L
98 85 115
L44655-01LFM LFM 06/14/18 13:12 MS180522-2 .0501 U .05002 m9/L 100 70 130
L44655-01LFMD LFMD 06/14/18 13:13 MS180522-2 .0501 U 051 m9/L 102 70 130 2 20
L44642-1806221021
Page 5 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Barium, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 1.9775 mg/L 99 95 105
WG4499811CB ICB 06/20/18 17:08 U mg/L -0.009 0.009
WG449789LRB LRB 06/20/18 17:24 U mg/L -0.0066 0.0066
WG449789LFB LFB 06/20/18 17:27 11180608-2 .5025 .5027 mg/L 100 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 .5025 .007 .5068 mg/L 99 70 130
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 .5025 .007 .5066 mg/L 99 70 130 0 20
Beryllium, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06/14/18 12:59 MS180423-2 .05 .048886 mg/L 98 90 110
WG4494701CB ICB 06/14/18 13:01 U mg/L-0.00015 0.00015
WG448814LRB LRB 06/14/18 13:04 U mg/L -0.00011 0.00011
WG448814LFB LFB 06/14/18 13:05 MS180522-2 .05035 .049414 mg/L 98 85 115
L44655-01LFM LFM 06/14/18 13:12 MS180522-2 .05035 U .049949 mg/L 99 70 130
L44655-01LFMD LFMD 06/14/18 13:13 MS180522-2 .05035 U .050048 mg/L 99 70 130 0 20
Cadmium, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 2.0013 mg/L 100 95 105
WG4499811CB ICB 06/20/18 17:08 U mg/L -0.015 0.015
WG449789LRB LRB 06/20/18 17:24 U mg/L -0.011 0.011
WG449789LFB LFB 06/20/18 17:27 11180608-2 .4975 .5002 mg/L 101 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 .4975 U .5008 mg/L 101 70 130
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 .4975 U .4993 mg/L 100 70 130 0 20
Calcium, dissolved
M200.7 ICP
ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower .per RPD Limit Qual
WG449759
WG4497591CV ICV 06/19/18 4:29 11180612-1 100 99.55 mg/L 100 95 105
WG4497591CB ICB 06/19/184:35 U mg/L -0.3 0.3
WG449759LFB LFB 06/19/184:47 11180608-2 68.22088 68.74 mg/L 101 85 115
L44826-01AS AS 06/19/18 5:15 11180608-2 68.22088 100 164.6 mg/L 95 85 115
L44826-01ASD ASD 06/19/18 5:24 11180608-2 68.22088 100 165.4 mg/L 96 85 115 0 20
Chloride
SM4500CI-E
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449717
WG4497171CB ICB 06/18/18 12:18
WG4497171CV ICV 06/18/18 12:18 W1180530-1
WG449717LFB1 LFB 06/18/18 13:18 W1171229-5
L44622-03DUP DUP 06/18/18 13:20
L44642-01AS AS 06/18/18 13:20 W1171229-5
WG449717LFB2 LFB 06/18/18 13:35 W1171229-5
U mg/L -1.5 1.5
54.89 58.22 mg/L 106 90 110
30.03 32.97 mg/L 110 90 110
22 21.58 mg/L
30.03 10.8 43.16 mg/L 108 90 110
30.03 31.51 mg/L 105 90 110
2 20
L44642-1806221021
Page 6 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Chromium, dissolved
M200.7 ICP
ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449759
W G4497591CV ICV 06/19/18 4:29 11180612-1
WG4497591CB ICB 06/19/18 4:35
WG449759LFB LFB 06/19/18 4:47 11180608-2
L44826-01AS AS 06/19/18 5:15 11180608-2
L44826-01ASD ASD 06/19/18 5:24 11180608-2
2 1.968 mg/L 98 95 105
U mg/L -0.03 0.03
.5 .519 m9/1- 104 85 115
5 U .515 mg/L 103 85 115
.5 U .525 mg/L 105 85 115 2 20
Conductivity @25C
SM2510B
QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449279
WG449279LCSW2 LCSW 06/12/18 16:01 PCN55811
L44675-01DUP DUP 06/12/18 18:08
WG449279LCSW5 LCSW 06/12/18 19:36 PCN55811
WG449279LCSW8 LCSW 06/12/18 22:56 PCN55811
WG449279LCSW11 LCSW 06/13/18 1:51 PCN55811
WG449279LCSW14 LCSW 06/13/18 5:28 PCN55811
1410 1460 umhos/cm 104 90 110
263 260 umhos/cm
1410 1450 umhos/cm 103 90 110
1410 1450 umhos/cm 103 90 110
1410 1440 umhos/cm 102 90 110
1410 1430 umhos/cm 101 90 110
1 20
Copper, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 1.958 mg/L 98 95 105
WG4499811CB ICB 06/20/18 17:08 U mg/L -0.03 0.03
WG449789LRB LRB 06/20/18 17:24 U mg/L -0.022 0.022
WG449789LFB LFB 06/20/18 17:27 11180608-2 .4975 .501 mg/L 101 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 .4975 U .499 m9/1- 100 70 130
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 .4975 U .496 m9/1- 100 70 130 1 20
Cyanide, total
M335.4 - Colorimetric w/ distillation
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec%
RPD Limit Qual
WG449533
WG4495331CV ICV 06/14/18 22:06 W1180613-2 .3003 .2821 mg/L 94 90 110
WG4495331CB ICB 06/14/18 22:07 U mg/L -0.003 0.003
WG449535
WG449446LRB LRB 06/14/18 23:37 U mg/L -0.003 0.003
WG449446LFB LFB 06/14/18 23:37 W118060818-2 .2 .1824 mg/L 91 90 110
L44569-10DUP DUP 06/14/18 23:39 U U mg/L 0 20 RA
L44569-11LFM LFM 06/14/1823:41 W118060818-2 .2 U .1892 mg/L 95 90 110
Fluoride
SM4500E-C
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% RPD Limit Qual
WG449719
WG4497191CV ICV 06/18/18 17:15 WC180611-13 1.996 1.995 m9/L 100 95 105
WG4497191CB ICB 06/18/18 17:21 U mg/L -0.15 0.15
WG449719LFB1 LFB 06/18/18 17:30 WC180508-10 5.015 5 mg/L 100 90 110
L42793-17AS AS 06/18/18 17:46 WC180508-10 5.015 .31 5.178 mg/L 97 90 110
L42793-17ASD ASD 06/18/18 17:54 WC180508-10 5.015 .31 5.1 mg/L 96 90 110 2 20
WG449719LFB2 LFB 06/18/18 20:39 WC180508-10 5.015 4.953 mg/L 99 90 110
L44642-1806221021
Page 7 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Iron, total recoverable
M200.7 ICP
ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 1.937 mg/L 97 95 105
WG4499811CB ICB 06/20/18 17:08 U mg/L -0.06 0.06
WG449789LRB LRB 06/20/18 17:24 U mg/L -0.044 0.044
WG449789LFB LFB 06/20/18 17:27 11180608-2 1.0011 1.008 mg/L 101 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 1.0011 .15 1.166 mg/L 101 70 130
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 1.0011 .15 1.16 mg/L 101 70 130 1 20
Lead, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06/14/18 12:59 MS180423-2 .05 .05177 mg/L 104 90 110
WG4494701CB ICB 06/14/18 13:01 U mg/L-0.0003 0.0003
WG448814LRB LRB 06/14/18 13:04 U mg/L -0.00022 0.00022
WG448814LFB LFB 06/14/18 13:05 MS180522-2 .0496 .04922 mg/L 99 85 115
L44655-01LFM LFM 06/14/18 13:12 MS180522-2 .0496 .0018 .05104 mg/L 99 70 130
L44655-01LFMD LFMD 06/14/18 13:13 MS180522-2 .0496 .0018 .05107 mg/L 99 70 130 0 20
Magnesium, dissolved
M200.7 ICP
ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449759
WG4497591CV ICV 06/19/184:29 11180612-1 100 99.45 mg/L 99 95 105
WG4497591CB ICB 06/19/184:35 U mg/L -0.6 0.6
WG449759LFB LFB 06/19/184:47 11180608-2 50.05667 48.81 mg/L 98 85 115
L44826-01AS AS 06/19/18 5:15 11180608-2 50.05667 7.3 56.86 mg/L 99 85 115
L44826-01ASD ASD 06/19/18 5:24 11180608-2 50.05667 7.3 56.85 mg/L 99 85 115 0 20
Manganese, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 1.9818 mg/L 99 95 105
WG4499811CB ICB 06/20/18 17:08 U mg/L -0.015 0.015
WG449789LRB LRB 06/20/18 17:24 U mg/L -0.011 0.011
WG449789LFB LFB 06/20/18 17:27 11180608-2 .5005 .508 mg/L 101 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 .5005 U .5119 mg/L 102 70 130
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 .5005 U .5107 mg/L 102 70 130 0 20
Mercury, total
M245.1 CVAA
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449591
WG4495911CV1 ICV 06/16/18 10:54 HG180607-3 .004995
WG4495911CB ICB 06/16/18 10:57
WG449593
.00488 mg/L 98 95 105
U mg/L-0.0002 0.0002
WG449593LRB LRB 06/16/18 11:32 U mg/L-0.00044 0.00044
WG449593LFB LFB 06/16/18 11:33 HG180530-3 .002002 .00184 mg/L 92 85 115
L44816-01LFM LFM 06/16/18 11:39 HG180530-3 .002002 U .0019 mg/L 95 85 115
L44816-01LFMD LFMD 06/16/18 11:40 HG180530-3 .002002 U .00187 mg/L 93 85 115 2 20
L44642-1806221021
Page 8 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Nickel, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
W G449981 ICV ICV 06/20/18 17:01 6180612-1
WG4499811CB ICB 06/20/18 17:08
WG449789LRB LRB 06/20/18 17:24
WG449789LFB LFB 06/20/18 17:27 11180608-2
L44799-01LFM LFM 06/20/18 17:37 11180608-2
L44799-01 LFMD LFMD 06/20/18 17:40 11180608-2
2.004 1.9792 mg/L 99 95 105
U mg/L -0.024 0.024
U mg/L-0.0176 0.0176
.5015 .51 mg/L 102 85 115
.5015 U .5151 mg/L 103 70 130
.5015 U .5095 mg/L 102 70 130 1 20
Nitrate/Nitrite as N, dissolved
M353.2 - Automated Cadmium Reduction
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upp- RPD Limit Qual
WG448576
WG4485761CV ICV 06/01/18 20:47 W1180301-7 2.416 2.415 mg/L 100 90 110
WG4485761CB ICB 06/01/18 20:49 U mg/L -0.02 0.02
WG448576LFB1 LFB 06/01/18 20:54 W1180103-12 2 2.032 mg/L 102 90 110
WG448576LFB2 LFB 06/01/18 21:34 W1180103-12 2 2.045 mg/L 102 90 110
L44614-02AS AS 06/01/18 21:41 W1180103-12 2 U 1.899 mg/L 95 90 110
L44622-01DUP DUP 06/01/18 21:43 U U mg/L 0 20 RA
Nitrite as N, dissolved
M353.2 - Automated Cadmium Reduction
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG448576
WG4485761CV ICV 06/01/18 20:47 W1180301-7
WG4485761CB ICB 06/01/18 20:49
WG448576LFB1 LFB 06/01/18 20:54 W1180103-12
WG448576LFB2 LFB 06/01/18 21:34 W1180103-12
L44614-02AS AS 06/01/18 21:41 W1180103-12
L44622-01DUP DUP 06/01/1821:43
pH (lab)
.609 .621 mg/L 102 90 110
U mg/L -0.01 0.01
1 1.012 mg/L 101 90 110
1 1.032 mg/L 103 90 110
1 U .59 mg/L 59 90 110 M2
U U mg/L 0 20 RA
SM4500H+ B
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449279
WG449279LCSW1 LCSW 06/12/18 15:59 PCN54162
L44675-01DUP DUP 06/12/18 18:08
WG449279LCSW4 LCSW 06/12/18 19:34 PCN54162
WG449279LCSW7 LCSW 06/12/18 22:54 PCN54162
WG449279LCSW10 LCSW 06/13/18 1:49 PCN54162
WG449279LCSW13 LCSW 06/13/18 5:26 PCN54162
Phosphorus, total
6.01 6.1 units 101 5.9 6.1
8.3 8.3 units
6.01 6.1 units 101 5.9 6.1
6.01 6 units 100 5.9 6.1
6.01 6 units 100 5.9 6.1
6.01 6 units 100 5.9 6.1
M365.1 - Auto Ascorbic Acid (digest)
0 20
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449264
WG4492641CV ICV 06/12/18 13:28 W1180601-8 .65228 .651 mg/L 100 90 110
WG4492641CB ICB 06/12/18 13:30 U mg/L
WG449274
-0.02
0.02
WG448844LRB LRB 06/12/18 15:25 U mg/L -0.02 0.02
WG448844LFB LFB 06/12/18 15:26 W1180605-7 .5 .492 mg/L 98 90 110
L44605-02LFM LFM 06/12/18 15:28 W1180605-7 .5 U .505 m9/1- 101 90 110
L44613-01DUP DUP 06/12/18 15:30 .43 .374 mg/L
14 20
L44642-1806221021
Page 9 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Potassium, dissolved
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN
QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449759
W G4497591CV
W G4497591CB
WG449759LFB
L44826-01AS
L44826-01ASD
ICV
ICB
LFB
AS
ASD
06/19/18 4:29
06/19/18 4:35
06/19/18 4:47
06/19/18 5:15
06/19/18 5:24
11180612-1
11180608-2
11180608-2
11180608-2
20
99.72934
99.72934
99.72934
6.3
6.3
19.88
U
100
109.4
109.7
mg/L
mg/L
mg/L
mg/L
mg/L
99 95
-0.6
100 85
103 85
104 85
105
0.6
115
115
115 0 20
Residue, Filterable (TDS) @180C
SM2540C
QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG448864
W G448864PB W
WG448864LCSW
L44675-01 DUP
PBW
LCSW
DUP
06/06/18 13:45
06/06/18 13:46 PCN55373
06/06/18 14:01
260
Residue, Non -Filterable (TSS) @105C SM2540D
U
262
194 196
mg/L
mg/L 101
mg/L
-20 20
80 120
1 10
ACZ ID
Type Analyzed PCN/SCN
QC Sample Found Units Rec% Lower
• Limit Qual
WG448878
W G448878PB W
WG448878LCSW
L44642-01 DUP
PBW
LCSW
DUP
06/06/18 17:00
06/06/18 17:02 PCN55373
06/06/18 17:31
160
Selenium, total recoverable M200.8 ICP-MS
mg/L
mg/L 98
mg/L
-15
15
80 120
0 10 RA
ACZ ID
Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
W G4494701CV
W G4494701CB
WG448814LRB
WG448814LFB
L44655-01 LFM
L44655-01 LFMD
ICV 06/14/18 12:59 MS180423-2 .05
ICB 06/14/18 13:01
LRB 06/14/18 13:04
LFB 06/14/18 13:05 MS180522-2 .05005
LFM 06/14/18 13:12 MS180522-2 .05005
LFMD 06/14/18 13:13 MS180522-2 .05005
.0545
U
U
.0489
U .0492
U .0504
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
109 90
-0.003
-0.0022
98 85
98 70
101 70
110
0.003
0.0022
115
130
130 2 20
Silica, dissolved
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN
QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449759
W G4497591CV
W G4497591CB
WG449759LFB
L44826-01AS
L44826-01ASD
ICV 06/19/18 4:29 11180612-1 42.8
ICB 06/19/18 4:35
LFB 06/19/18 4:47 11180608-2 21.415
AS 06/19/18 5:15 11180608-2 21.415
ASD 06/19/18 5:24 11180608-2 21.415
52.5
52.5
41.44
U
22.89
72.86
72.46
mg/L
mg/L
mg/L
mg/L
mg/L
97 95
-0.6
107 85
95 85
93 85
105
0.6
115
115
115 1 20
L44642-1806221021
Page 10 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Silver, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
W G449981 ICV ICV 06/20/18 17:01 6180612-1
WG4499811CB ICB 06/20/18 17:08
WG449789LRB LRB 06/20/18 17:24
WG449789LFB LFB 06/20/18 17:27 11180608-2
L44799-01LFM LFM 06/20/18 17:37 11180608-2
L44799-01 LFMD LFMD 06/20/18 17:40 11180608-2
1.001 1.005 mg/L 100 95 105
U mg/L -0.03 0.03
U mg/L -0.022 0.022
.5 .497 mg/L 99 85 115
.5 U .493 mg/L 99 70 130
.5 U .493 mg/L 99 70 130 0 20
Sodium, dissolved
M200.7 ICP
ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Uppe RPD Limit Qual
WG449759
WG4497591CV ICV 06/19/18 4:29 11180612-1 100 100.44 mg/L 100 95 105
WG4497591CB ICB 06/19/184:35 U mg/L -0.6 0.6
WG449759LFB LFB 06/19/184:47 11180608-2 100.6711 101.8 mg/L 101 85 115
L44826-01AS AS 06/19/18 5:15 11180608-2 100.6711 22.2 125.2 mg/L 102 85 115
L44826-01ASD ASD 06/19/18 5:24 11180608-2 100.6711 22.2 125.4 mg/L 103 85 115 0 20
Sulfate
SM4500 SO4-D
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449698
WG449698PBW PBW 06/18/18 11:50 U mg/L
WG449698LCSW LCSW 06/18/18 11:53 WC170902-4 100 102 mg/L 102 80 120
L44860-05DUP DUP 06/18/18 12:32 290 281 mg/L
Thallium, total recoverable
M200.8 ICP-MS
-30 30
3 20
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06/14/18 12:59 MS180423-2 .05 .0528 mg/1- 106 90 110
WG4494701CB ICB 06/14/18 13:01 U mg/L-0.0003 0.0003
WG448814LRB LRB 06/14/18 13:04 U mg/L-0.00022 0.00022
WG448814LFB LFB 06/14/18 13:05 MS180522-2 .0501 .0504 mg/L 101 85 115
L44655-01LFM LFM 06/14/18 13:12 MS180522-2 .0501 U .05032 mg/L 100 70 130
L44655-01LFMD LFMD 06/14/18 13:13 MS180522-2 .0501 U .05054 mg/L 101 70 130 0 20
Turbidity
M180.1 - Nephelometric
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG448570
WG4485701CV ICV 06/01/18 16:21 PCN54180
WG4485701CV1 ICV 06/01/18 16:23 PCN54180
WG4485701CB ICB 06/01/18 16:24
L44642-01DUP DUP 06/01/18 16:33
205 213 NTU 104 90 110
205 213 NTU 104 90 110
U NTU -0.3 0.3
U U NTU 0 20 RA
L44642-1806221021
Page 11 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Uranium, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCN/SCN
QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06/14/18 12:59 MS180423-2 .05 .05049 mg/L 101 90 110
WG4494701CB ICB 06/14/18 13:01 U mg/L-0.0003 0.0003
WG448814LRB LRB 06/14/18 13:04 U mg/L-0.00022 0.00022
WG448814LFB LFB 06/14/18 13:05 MS180522-2 .05 .04982 mg/L 100 85 115
L44655-01LFM LFM 06/14/18 13:12 MS180522-2 .05 .0017 .05247 mg/ 102 70 130
L44655-01LFMD LFMD 06/14/18 13:13 MS180522-2 .05 .0017 .05293 mg/L 102 70 130 1 20
Zinc, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 2.015 mg/L 101 95 105
WG4499811CB ICB 06/20/18 17:08 U mg/L -0.03 0.03
WG449789LRB LRB 06/20/18 17:24 U mg/L -0.022 0.022
WG449789LFB LFB 06/20/18 17:27 11180608-2 .4942 .524 mg/L 106 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 .4942 U .522 mg/1- 106 70 130
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 .4942 U .522 mg/1- 106 70 130 0 20
L44642-1806221021 Page 12 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic Extended
Qualifier Report
ACZ Project ID: L44642
ACZ ID WORKNUM PARAMETER
METHOD
QUAL DESCRIPTION
L44642-01 RG639152 Corrosivity (calc.)
WG449535 Cyanide, total
WG448576 Nitrate/Nitrite as N, dissolved
Nitrite as N, dissolved
SM 2330 - CaCO3 SI
M335.4 - Colorimetric w/
distillation
M353.2 - Automated Cadmium
Reduction
M353.2 - Automated Cadmium
Reduction
M353.2 - Automated Cadmium
Reduction
M353.2 - Automated Cadmium
Reduction
M353.2 - Automated Cadmium
Reduction
WG448878 Residue, Non -Filterable (TSS) @105C SM2540D
WG448570 Turbidity
M180.1 - Nephelometric
ZZ
RA
RA
ZU
M2
RA
ZU
RA
RA
Laboratory measured pH and temperature were used in this
calculation. Sampler did not report either field pH, field
temperature, or both.
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL).
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL).
Analysis date/time preceeds filter date/time. A portion of
sample was filtered and analyzed prior to the creation of a
Filter workgroup.
Matrix spike recovery was low, the recovery of the
associated control sample (LCS or LFB) was acceptable.
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL).
Analysis date/time preceeds filter date/time. A portion of
sample was filtered and analyzed prior to the creation of a
Filter workgroup.
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL).
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL).
REPAD.15.06.05.01
L44642-1806221021 Page 13 of 22
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Project ID:
Sample ID:
Locator:
181-053.000
WELL TEPEOL
RadioChemistry
Analytical Results
ACZ Sample ID:
Date Sampled:
Date Received:
Sample Matrix:
L44642-01
05/31/18 14:56
06/01/18
Drinking Water
Gross Alpha & Beta
M900.0
Alpha
Beta
Prep Method:
Measure Date
Prep Date
Result Error(+/-) LLD
Units XQ Analyst
06/16/18 0:07
06/16/18 0:07
7.3
3.3
2.4
3.3 3.4 3.4
pCi/L
pCi/L
slm/jlg
slm/jlg
REPRC.02.06.05.01
* Please refer to Qualifier Reports for details.
L44642-1806221021 Page 14 of 22
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Radiochemistry
Reference
Report Header Explanations
Batch A distinct set of samples analyzed at a specific time
Error(+/-) Calculated sample specific uncertainty
Found Value of the QC Type of interest
Limit Upper limit for RPD, in %.
LCL Lower Control Limit, in % (except for LCSS, mg/Kg)
LLD Calculated sample specific Lower Limit of Detection
PCN/SCN A number assigned to reagents/standards to trace to the manufacturer's certificate of analysis
PQL Practical Quantitation Limit
QC True Value of the Control Sample or the amount added to the Spike
Rec Amount of the true value or spike added recovered, in % (except for LCSS, mg/Kg)
RER Relative Error Ratio, calculation used for Dup. QC taking into account the error factor.
RPD Relative Percent Difference, calculation used for Duplicate QC Types
UCL Upper Control Limit, in % (except for LCSS, mg/Kg)
Sample Value of the Sample of interest
QC Sample Types
DUP
LCSS
LCSW
Sample Duplicate
Laboratory Control Sample - Soil
Laboratory Control Sample - Water
MS/MSD
PBS
PBW
Matrix Spike/Matrix Spike Duplicate
Prep Blank - Soil
Prep Blank - Water
QC Sample Type Explanations
Blanks
Control Samples
Duplicates
Matrix Spikes
Verifies that there is no or minimal contamination in the prep method procedure.
Verifies the accuracy of the method, including the prep procedure.
Verifies the precision of the instrument and/or method.
Determines sample matrix interferences, if any.
ACZ Qualifiers (Qual)
H Analysis exceeded method hold time.
M EPA methodology, including those under SDWA, CWA, and RCRA
SM
D
RP
ESM
Standard Methods for the Examination of Water and Wastewater.
ASTM
DOE
DOE/ESM
Comments
(1)
(2)
(3)
(4)
Solid matrices are reported on a dry weight basis.
Preparation method: "Method" indicates preparation defined in analytical method.
QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations.
An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification
qualifier associated with the result.
For a complete list of ACZ's Extended Qualifiers, please click: http://www.acz.com/public/extquallist.pdf
REP003.09.12.01
L44642-1806221021
Page 15 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Radiochemistry QC
Summary
ACZ Project ID: L44642
Alpha
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low limits are in % Rec.
M900.0
Units: pCi/L
ACZ ID
Type Analyzed PCN/SCN QC Sample Error LLD Found Error LLD Rec% Lower Upper RPD/RER Limit Qual
WG449738
WG449728PBW PBW 06/16/18
WG449728LCSW LCSW 06/16/18 PCN55778
L44642-01DUP DUP-RPD 06/16/18
L44642-01DUP DUP-RER 06/16/18
L44703-02DUP DUP-RPD 06/16/18
L44736-05MS MS 06/16/18 PCN55778
Beta
M900.0
.06 0.83 1.1
100 100 8.7 1.7 100 67 144
7.3 3.3 2.4 9.6 3.6 2.2
7.3 3.3 2.4 9.6 3.6 2.2
4.8 3 2.5 4.8 3 2.5
100 2.9 2.3 5.7 85 8.9 4.6 82 67 144
2.2
27 20 RG
0.47 2
0 20
Units: pCi/L
ACZ ID
Type Analyzed PCN/SCN QC
Sample Error LLD Found Error LLD Rec% Lower Upper RPD/RER Limit Qual
WG449738
WG449728PBW PBW 06/16/18
WG449728LCSW LCSW 06/16/18 RC180320-10 100
L44642-01DUP DUP-RPD 06/16/18 3.3 3.4 3.4
L44642-01DUP DUP-RER 06/16/18 3.3 3.4 3.4
L44703-02DUP DUP-RPD 06/16/18 3.1 3 3
L44736-07MS MS 06/16/18 RC180320-10 100 3.9 3 7.3
2 2 1.9
3.8
92 6.2 2.6 92 82 122
8.5 3.5 3.1
8.5 3.5 3.1
3.6 3.4 3.4
100 7 7.8 96 82 122
88 20
1.07 2
15 20
RG
L44642-1806221021
Page 16 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
RadChem Extended
Qualifier Report
ACZ Project ID: L44642
ACZ ID WORKNUM PARAMETER METHOD QUAL DESCRIPTION
L44642-01 WG449738 Alpha
Beta
M900.0 RG Sample concentration is less than 5x LLD; RPD was not
used for data validation. Replicate Error Ratio (RER) is
less than 2. Precision judged to be in control.
M900.0 RG Sample concentration is less than 5x LLD; RPD was not
used for data validation. Replicate Error Ratio (RER) is
less than 2. Precision judged to be in control.
REPAD.1 5.06.05.01
L44642-1806221021 Page 17 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Certification
Qualifiers
ACZ Project ID: L44642
Metals Analysis
The following parameters are not offered for certification or are not covered by NELAC certificate #ACZ.
Barium, total recoverable
Cadmium, total recoverable
Chromium, dissolved
Copper, total recoverable
Nickel, total recoverable
Potassium, dissolved
Silver, total recoverable
Wet Chemistry
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
The following parameters are not offered for certification or are not covered by NELAC certificate #ACZ.
Chloride
Phosphorus, total
Residue, Non -Filterable (TSS) @105C
Sulfate
SM4500CI-E
M365.1 - Auto Ascorbic Acid (digest)
SM2540D
SM4500 SO4-D
REPAD.05.06.05.01
L44642-1806221021 Page 18 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
181-053.000
Sample
Receipt
ACZ Project ID: L44642
Date Received: 06/01/2018 11:05
Received By:
Date Printed:
6/4/2018
Receipt Verification
1) Is a foreign soil permit included for applicable samples?
2) Is the Chain of Custody form or other directive shipping papers present?
3) Does this project require special handling procedures such as CLP protocol?
4) Are any samples NRC licensable material?
5) If samples are received past hold time, proceed with requested short hold time analyses?
6) Is the Chain of Custody form complete and accurate?
7) Were any changes made to the Chain of Custody form prior to ACZ receiving the samples?
YES
NO
NA
Samples/Containers
8) Are all containers intact and with no leaks?
9) Are all labels on containers and are they intact and legible?
10) Do the sample labels and Chain of Custody form match for Sample ID, Date, and Time?
11) For preserved bottle types, was the pH checked and within limits? 1
12) Is there sufficient sample volume to perform all requested work?
13) Is the custody seal intact on all containers?
14) Are samples that require zero headspace acceptable?
15) Are all sample containers appropriate for analytical requirements?
16) Is there an Hg-1631 trip blank present?
17) Is there a VOA trip blank present?
18) Were all samples received within hold time?
YES NO NA
NA indicates Not Applicable
Chain of Custody Related Remarks
Client Contact Remarks
Shipping Containers
Cooler Id Temp(°C) Temp Rad(pR/Hr) Custody Seal
Criteria(°C) Intact?
3963
1.4 <=6.0
15
Yes
Was ice present in the shipment container(s)?
Yes - Wet ice was present in the shipment container(s).
Client must contact an ACZ Project Manager if analysis should not proceed for samples received
outside of their thermal preservation acceptance criteria.
REPAD LPII 2012-03
L44642-1806221021
Page 19 of 22
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
181-053.000
Sample
Receipt
ACZ Project ID: L44642
Date Received: 06/01/2018 11:05
Received By:
Date Printed: 6/4/2018
1 The preservation of the following bottle types is not checked at sample receipt: Orange (oil and
grease), Purple (total cyanide), Pink (dissolved cyanide), Brown (arsenic speciation), Sterile (fecal
coliform), EDTA (sulfite), HCI preserved vial (organics), Na2S2O3 preserved vial (organics), and
HG-1631 (total/dissolved mercury by method 1631).
REPAD LPII 2012-03
L44642-1806221021 Page 20 of 22
ACZ Laboratories, Inc./ --
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334449,3U l(1
Report to:
Name: SCOitSC,h(-6bQ(
Company: LA)(1 q\ L00.44( EUl[}n'OYS tOC-
E-mail: SiSC�1t ,ref e: „A„-1-Pr • (bin
Copy of Report to:
Name:
Company:
CHAIN of CUSTODY
Address: i %bkbradD Nve
G7\ rI\k1)crx1 cpr S, en gN?'oi
Telephone: q-3-1)-
E-mail:
Telephone:
Address:
If sample(s) received past holding time (HT), or if insufficient HT remains to complete YES
analysis before expiration, shall ACZ proceed with requested short HT analyses? NO
If "NO" then ACZ will contact client for further instruction. If neither -YES- nor NO is indicated, ACZ will proceed with the requested analyses, even if HT is expired, and data will be qu Bled
Are samples for SDWA Compliance Monitoring? Yes I I No
If yes, please include state forms. Results will be reported to PQL for Colorado.
Sampler's Name:
*Sampler's Signature:
PROJECT INFORMATION
Quote #:
Sampler's Site Information State Cip Zip code -6 ILO 22? Time Zone V i'Y\
"I attest to the authenticity and validity of this sample. I understand that intentionally mislabeling th time/date/location or
tampering with the sample in anyway, is considered fraud and punishable by State Law.
Po#: 61—DS3•Db0
Reporting state for compliance testing:
K1 IA
Check box if samples include NRC licensed material?
SAMPLE IDENTIFICATION DATE:TIME
Matrix
ANALYSES REQUESTED (attach kst or use quote number)
//7-
ArtAte-6-6
U
0
<z- E PEOz- S/303 a -30'01 Cu) 7
a
0
mimeiisakr
Matrix SW (Surface Water) GW (Ground Water) • WW (Waste Water) • DW (Drinking Wate ) SL (Sludge) • SO (Soil) OL (Oil) • Othe (Specify)
REMARKS
Please refer to ACZ's terms & conditions located on the reverse side of this COC.
RELINQUISHED BY: DATE:TIME RECEIVED BY: DATE:TIME
3 " 3 : N3 P^"
//CAS
L g3D
:0
6e24.0R 1
White - Return with sample. Yellow - Retain for your records.
Page 21 of 22
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Account: WRIGHT/Wright Water Engineers
Bottle Order: B039882
Bottle Order
Bottle List
Bill to Account:
Ship Date Requested:
Request Placed at:
Service Requested:
BiII to ACZ
05/18/2018
05/17/2018 14:23
UPS Ground
Sampling supplies
PACK Qty ACZ°Ii3''.
1 COC
2 SEAL
1 RETURN
7 LABELS
Type Description
Chain of Custody
Custody Seal
Return Address
Sample Labels
Chain of Custody, 1 for 10 samples.
Custody seals for cooler, two for each cooler.
Return Address label, one for each cooler.
ACZ supplied labels for sample containers
ACZ Coolers
Tracking Number
1Z8101300317193360
Quote number: WRIGHT-DW-2018
Sample Quantity: 1
PACK Qty
1
Type
GREEN
1 PURPLE
1 RAW
Analysis of Primary and Secondary inorganic DW paramaters -
,1"A O
ACZ is responsible for necessary sample filtering
ze Filter/./Preserve; Instruct[
125 ML Filtered/Nitri
250 ML Raw/NaOH
500 ML Raw
1 RED PC 250 ML Red pre -cleaned
Raw/Nitric
0 RED PC WM 1 L Red pre -cleaned wide
mouth Raw/Nitric
1 RED RAD 1000 ML Raw/Nitric
1 WHITE 250 ML Filtered
1 YELLOW 250 ML Raw/Sulfuric
Metals (dissolved except ICPMS) - This is a filtered sample.
Completely fill container.
Cyanide - Do not overfill as there is Sodium Hydroxide in the bottle.
Wet Chemistry (analyses that do not require preservative or
filtration) - Completely fill container.
Metals (total including ICPMS) - Do not overfill as there is Nitric
Acid in the bottle.
Metals (total ICPMS) - Do not overfill as there is Nitric Acid in the
bottle.
Radiochemistry (total) - Do not overfill as there is Nitric Acid in the
bottle.
Wet chemistry (dissolved) - This is a filtered sample. Completely fill
container.
For total wet chemistry analyses. Do not overfill as there is Sulfuric
Acid in the bottle.
Prepared By/Date:
sw
L44642-1806221021
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